Iodine trichloride

Base Information

• Chemical Name: Iodine trichloride
• CAS No.: 865-44-1
• Molecular Formula: Cl3I
• Molecular Weight: 233.264
• Hs Code.: 28121099
• European Community (EC) Number: 212-739-8
• UNII: 1E5KQ66TRQ
• DSSTox Substance ID: DTXSID3061219
• Nikkaji Number: J96.352F
• Wikipedia: Iodine(III) chloride,Iodine trichloride,Iodine_trichloride
• Wikidata: Q419622
• Mol file: 865-44-1.mol

Synonyms:Iodine trichloride;865-44-1;Iodine chloride (ICl3);trichloroiodine;trichloro-lambda3-iodane;UNII-1E5KQ66TRQ;1E5KQ66TRQ;EINECS 212-739-8;Cl3I;Jodtrichlorid;Cl3-I;Iodine trichloride, 97%;IODINE TRICHLORIDE [MI];DTXSID3061219;IODINE TRICHLORIDE [INCI];MFCD00036291;AKOS015853996;Iodine trichloride, SAJ first grade, >=96.0%;Iodine trichloride, SAJ special grade, >=97.0%;Q419622

Chemical Property of Iodine trichloride

Chemical Property:

• Appearance/Colour: Orange-yellow, deliquescent, crystalline powder.
• Vapor Pressure: 1.3 hPa (64 °C)
• Melting Point: -33oC
• Boiling Point: 77(分解)
• PSA: 0.00000
• Density: 3.11 g/cm3 (15 C)
• LogP: 2.95420
• Storage Temp.: 0-6°C
• Sensitive.: Light Sensitive
• Solubility.: Soluble with decomposition.
• Water Solubility.: decomposes in H2O; soluble alcohol, benzene [HAW93]
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 231.81103
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

99.9% ^*data from raw suppliers

Iodine trichloride for synthesis. CAS 865-44-1, EC Number 212-739-8, chemical formula ICl ., for synthesis ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,C
• Hazard Codes: C,T,O
• Statements: 34-9
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: ClI(Cl)Cl
• Uses: Iodine trichloride is used in organic synthesis as a chlorinating and iodinating agent to introduce chlorine and iodine into organic compounds producing their halogen derivatives. It also is used as a topical antiseptic. Iodine trichloride can be used to introduce iodine and chlorine in organic synthesis. It is also used as topical antiseptic and as laboratory reagent. Iodine trichloride is used as a chlorinatingand oxidizing agent. Chlorinating and oxidizing agent.
• Physical properties: Orange yellow triclinic crystals or fluffy powder; hygroscopic; density 3.111g/cm3at 15°C; sublimes at 64°C with decomposition; melts at 101°C at 16 atm;hydrolyzes in water; soluble in ethanol, carbon tetrachloride and benzene; soluble in concentrated hydrochloric acid but hydrolyzes in dilute acid.

Technology Process of Iodine trichloride

There total 46 articles about Iodine trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

iodine (7553-56-2,12190-71-5,8031-47-8) + chlorine (7782-50-5) → Iodine monochloride (7790-99-0) + iodine trichloride (865-44-1)

Guidance literature:

In neat (no solvent); passing dry chlorine over dry iodine;; distillation in stream of chlorine at 100-101.5°C;;

DOI:10.1021/ja01344a021

Reference yield:

antimonypentachloride (7647-18-9) → SbCl5*I + antimony(III) chloride (10025-91-9) + Iodine monochloride (7790-99-0) + antimony triiodide (7790-44-5) + iodine trichloride (865-44-1)

Guidance literature:

byproducts: antimony(V) chloroiodide; room temp.;

Reference yield:

antimony(V) chloride (7647-18-9) + iodine (7553-56-2,12190-71-5,8031-47-8) → antimony(III) chloride (10025-91-9) + Iodine monochloride (7790-99-0) + iodine trichloride (865-44-1)

Guidance literature:

In further solvent(s); I2 is dissolved in SbCl5 (reactn. proceeds with evolution of heat, the compounds SbCl3, ICl, ICl3 are formed in soln.;;

upstream raw materials:

nitrogen trichloride

iodine

sulfuryl dichloride

chlorine

Downstream raw materials:

iodine

sodium chloride

sodium sulfate

nickel(II) iodide

Refernces

• 1、 Kuvychko, Igor V.,Streletskii, Alexey V.,Shustova, Natalia B.,Seppelt, Konrad,Drewello, Thomas,Popov, Alexey A.,Strauss, Steven H.,Boltalina, Olga V.. "Soluble chlorofullerenes C60Cl2,4,6,8,10. synthesis, purification, compositional analysis, stability, and experimental/theoretical structure elucidation, including the X-ray structure of C1-C 60Cl10". . p. 6443 - 6462. Retrieved 2010.
• 2、 Willis, Robert E.,Clark, William W.. "Millimetr wave measurements of the rotational spectra of ClF, BrF, BrCl, ICl, and IBr". . p. 4946 - 4950. Retrieved 2007/10/02.