Technology Process of 2,6-Pyridinedicarboxamide, N,N'-bis[2-(methylthio)phenyl]-
There total 1 articles about 2,6-Pyridinedicarboxamide, N,N'-bis[2-(methylthio)phenyl]- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
N,N'-bis(2-mercaptophenyl)pyridine-2,6-dicarboxamide;
With
triethylamine;
In
chloroform;
for 0.0833333h;
Glovebox;
Schlenk technique;
methyl iodide;
In
chloroform; acetonitrile;
at 20 ℃;
for 2h;
Glovebox;
Schlenk technique;
Sealed tube;
Inert atmosphere;
DOI:10.1021/acs.inorgchem.9b01074
- Guidance literature:
-
With
NaH;
In
N,N-dimethyl-formamide;
byproducts: NaCl; all manipulations by standart Schlenk techniques; NaH added to soln. of ligand, stirred, soln. of Fe complex added, stirred for 2 h at 25°C; solvent removed in vac., residue dissolved in MeCN, filtered, Et2O addedto filtrate, stirred at -20°C for 48 h, filtered, dried in vac.;
DOI:10.1002/ejic.200390067
- Guidance literature:
-
With
NaH;
In
N,N-dimethyl-formamide;
ligand was dissolved in DMF, NaH was added, stirred for 10 min, Co-complex was added, heated at 60°C for 1.5 h, Et4NCl was added; DMF was removed by vac. distillation, dissolved in MeCN, filtered, acetone was slowly diffused, 48 h;
DOI:10.1016/S0020-1693(01)00523-0
