Technology Process of Phosphine, [3,5-bis(trifluoromethyl)phenyl]bis(1-methylethyl)-
There total 1 articles about Phosphine, [3,5-bis(trifluoromethyl)phenyl]bis(1-methylethyl)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
3,6-bis(trifluoromethyl)bromobenzene;
With
magnesium; ethylene dibromide;
In
diethyl ether;
for 2h;
Heating;
Chlorodiisopropylphosphane;
In
diethyl ether;
DOI:10.1016/j.jorganchem.2004.11.053
- Guidance literature:
-
In
benzene;
(Ar); std. Schlenk technique; soln. of ligand in C6H6 was added dropwiseto soln. of Co complex in C6H6; mixt. was refluxed and stirred for 6 h; cooled to 25°C; solvent removed (vac.); washed (pentane); crystd.(CH2Cl2/pentane, 1/5); elem. anal.;
DOI:10.1016/j.jorganchem.2004.11.053
- Guidance literature:
-
With
Na2CO3;
In
methanol;
RuCl3*3H2O (1.9 mmol) was mixed with a ligand (6 mmol) and Na2CO3 (2 mmol); methanol was added; the soln. was refluxed at 70°C for 8 h; under Ar; volatiles were removed in vac.; the solid was dissolved in benzene and filtered via glass wool; benzene was removed in vac. and the residue was washed with pentane; NMR-, IR studies;
DOI:10.1021/ic000500t
