Silane, trimethyl(4-phenyl-1-butynyl)-

Base Information

• Chemical Name: Silane, trimethyl(4-phenyl-1-butynyl)-
• CAS No.: 40277-01-8
• Molecular Formula: C13H18Si
• Molecular Weight: 202.371
• Mol file: 40277-01-8.mol

Synonyms:4-Phenyl-1-trimethylsilyl-butin-(1);4-Phenyl-1-(trimethylsilyl)-1-butyne;Trimethyl-(4-phenyl-1-butyin-1-yl)-silan;1-(trimethylsilyl)-4-phenyl-1-butyne;trimethyl(4-phenylbut-1-ynyl)silane;

Chemical Property of Silane, trimethyl(4-phenyl-1-butynyl)-

Chemical Property:

• Boiling Point: 249.3±19.0 °C(Predicted)
• PSA: 0.00000
• Density: 0.904±0.06 g/cm3(Predicted)
• LogP: 3.50000

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silane, trimethyl(4-phenyl-1-butynyl)-

There total 15 articles about Silane, trimethyl(4-phenyl-1-butynyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

iodobenzene (591-50-4) + C7H13ISiZn (116897-00-8) → 1-(trimethylsilyl)-4-phenyl-1-butyne (40277-01-8)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; copper(l) iodide; In tetrahydrofuran; N,N-dimethyl acetamide; at 80 ℃;

DOI:10.1002/ejoc.201201329

Reference yield: 93.0%

chloro-trimethyl-silane (75-77-4) + 4-Phenyl-1-butyne (16520-62-0) → 1-(trimethylsilyl)-4-phenyl-1-butyne (40277-01-8)

Guidance literature:

4-Phenyl-1-butyne; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h; Inert atmosphere;

chloro-trimethyl-silane; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 1.16h; Inert atmosphere;

DOI:10.1002/adsc.201300765

Reference yield: 73.0%

4-methyl-N'-(2-phenylethylidene)benzenesulfonohydrazide (17336-58-2) + trimethylsilylacetylene (1066-54-2) → 1-(trimethylsilyl)-4-phenyl-1-butyne (40277-01-8)

Guidance literature:

With copper(l) iodide; lithium tert-butoxide; In 1,4-dioxane; at 110 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ja3004792

upstream raw materials:

chloro-trimethyl-silane

4-Phenyl-1-butyne

trimethyl(prop-1-ynyl)silane

iodomethylbenzene

Downstream raw materials:

C₁₆H₁₄S

2,2-Dichloro-5-(2-phenylethyl)-4-(trimethylsilyl)-3(2H)-furanone

2-(4-phenyl-1-trimethylsilanyl-butyl)-[1,3,2]dioxaborinane