2-Propenoic acid, 3-(1,3-benzodioxol-5-yl)-, methyl ester, (E)-

Base Information

• Chemical Name: 2-Propenoic acid, 3-(1,3-benzodioxol-5-yl)-, methyl ester, (E)-
• CAS No.: 40918-96-5
• Molecular Formula: C11H10O4
• Molecular Weight: 206.198
• Hs Code.: 2932999099
• Mol file: 40918-96-5.mol

Synonyms:2-hydroxy-3-methoxy-trans-cinnamic acid methyl ester;methyl (2E)-3-(2-hydroxy-3-methoxyphenyl)acrylate;2-hydroxy-3-methoxy-(E)-cinnamic acid methyl ester;2-Hydroxy-3-methoxy-trans-zimtsaeure-methylester;2-Propenoic acid,3-(2-hydroxy-3-methoxyphenyl)-,methyl ester,(2E);methyl E-3-<3,4-(methylenedioxy)phenyl>acrylate;Methyl (E)-3-(3,4-methylenedioxyphenyl)propenoate;(E)-methyl 3-(benzo[d][1,3]dioxol-5-yl)acrylate;(E)-3,4-methylenedioxycinnamic acid methyl ester;(E)-methyl 3-(1,3-benzodioxol-5-yl)prop-2-enoate;

Chemical Property of 2-Propenoic acid, 3-(1,3-benzodioxol-5-yl)-, methyl ester, (E)-

Chemical Property:

• PSA: 44.76000
• LogP: 1.60150

Purity/Quality:

99% ^*data from raw suppliers

METHYL 3-(1,3-BENZODIOXOL-5-YL)ACRYLATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Propenoic acid, 3-(1,3-benzodioxol-5-yl)-, methyl ester, (E)-

There total 23 articles about 2-Propenoic acid, 3-(1,3-benzodioxol-5-yl)-, methyl ester, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

piperonal (120-57-0,30024-74-9) + trimethyl phosphonoacetate (5927-18-4) → methyl (2E)-3-(1,3-benzodioxol-5-yl)acrylate (40918-96-5)

Guidance literature:

trimethyl phosphonoacetate; With sodium hydride; In tetrahydrofuran; paraffin oil; at 0 - 20 ℃; for 0.5h; Inert atmosphere;

piperonal; In tetrahydrofuran; paraffin oil; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1002/ejoc.202100026

Reference yield: 99.0%

methanol (67-56-1) + 3,4-methylenedioxy-trans-cinnamic acid (2373-80-0,38489-76-8) → methyl (2E)-3-(1,3-benzodioxol-5-yl)acrylate (40918-96-5)

Guidance literature:

With sulfuric acid; Heating;

DOI:10.1021/jo800901r

Reference yield: 99.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + 3,4-methylenedioxy-trans-cinnamic acid (2373-80-0,38489-76-8) → methyl (2E)-3-(1,3-benzodioxol-5-yl)acrylate (40918-96-5)

Guidance literature:

In methanol; diethyl ether; at 20 ℃; for 0.25h; Inert atmosphere;

DOI:10.1002/anie.201712088

upstream raw materials:

piperonal

acetic acid methyl ester

3t-benzo[1,3]dioxol-5-yl-N-phenyl-acrylimidic acid methyl ester

methanol

Downstream raw materials:

(E)-3-(benzo[d][1,3]dioxol-5-yl)prop-2-en-1-ol

3,4-methylenedioxy-trans-cinnamic acid

caffeic acid

(3R*,4R*)-3-(3,4,5-trimethoxybenzyl)-4-(3,4-methylenedioxybenzyl)-4,5-dihydro-2(3H)-furanone

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 40918-96-5 2-Propenoic acid, 3-(1,3-benzodioxol-5-yl)-, methyl ester, (E)-

Send

Send

Metric Ton KG G Pound L ML

Send

Send