Dichloro-methyl-trimethylsilylsilane

Base Information

• Chemical Name: Dichloro-methyl-trimethylsilylsilane
• CAS No.: 4518-99-4
• Molecular Formula: C4H12Cl2Si2
• Molecular Weight: 187.216
• European Community (EC) Number: 628-873-9
• Nikkaji Number: J1.636.178J
• Mol file: 4518-99-4.mol

Synonyms:dichloro-methyl-trimethylsilylsilane;1,1,1,2-Tetramethyl-2,2-dichlorodisilane;1,1-dichlorotetramethyldisilane;4518-99-4;SCHEMBL331164;EINECS 254-449-4;1,1-DICHLORO-1,2,2,2-TETRAMETHYLDISILANE

Chemical Property of Dichloro-methyl-trimethylsilylsilane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 185.9854588
• Heavy Atom Count: 8
• Complexity: 84.5

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(C)[Si](C)(Cl)Cl

Technology Process of Dichloro-methyl-trimethylsilylsilane

There total 1 articles about Dichloro-methyl-trimethylsilylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1,2,2-tetrachloro-1,2-dimethyldisilane (4518-98-3) + methylmagnesium chloride (676-58-4) → pentamethylchlorodisilane (1560-28-7) + 1,1-dichlorotetramethyldisilane (4518-99-4)

Guidance literature:

In tetrahydrofuran; at -40 - 20 ℃; for 18h;

DOI:10.1002/chem.201603842

Reference yield: 61.0%

ethanol (64-17-5) + 1,1-dichlorotetramethyldisilane (4518-99-4) → 1,1-diethoxytetramethyldisilane (56998-73-3)

Guidance literature:

In pyridine; diethyl ether; at 36 ℃; for 5h;

Reference yield: 5.5%

1,1-dichlorotetramethyldisilane (4518-99-4) + (S)-methyl(1-naphthyl)phenylsilyltrimethylstannane (637765-12-9,313062-51-0) → (1R,3R)-1,3-di(1-naphthyl)-1,3-diphenyl-2-trimethylsilyl-1,2,3-trimethyltrisilane + (1S,3S)-1,3-di(1-naphthyl)-1,3-diphenyl-2-trimethylsilyl-1,2,3-trimethyltrisilane

Guidance literature:

(S)-methyl(1-naphthyl)phenylsilyltrimethylstannane; With methyllithium; In tetrahydrofuran; toluene; at -78 ℃;

1,1-dichlorotetramethyldisilane; In tetrahydrofuran; toluene; at -78 ℃;

DOI:10.1016/S0022-328X(03)00169-4

upstream raw materials:

1,1,2,2-tetrachloro-1,2-dimethyldisilane

methylmagnesium chloride

Downstream raw materials:

1,1-Dimethoxytetramethyldisilan

1-phenyl-1-vinyltetramethyldisilane

1-(trimethylsilyl)-1-methyl-2,5-diphenylsilacyclopentadiene

dichlorotetramethyldisiloxane

Refernces