1,1-Diphenoxyethane

Base Information

• Chemical Name: 1,1-Diphenoxyethane
• CAS No.: 4850-74-2
• Molecular Formula: C14H14O2
• Molecular Weight: 214.264
• UNII: 7493SP153D
• Nikkaji Number: J465.509E
• Wikidata: Q27266260
• Mol file: 4850-74-2.mol

Synonyms:1,1-Diphenoxyethane;Acetaldehyde, diphenyl acetal;Benzene, 1,1'-(ethylidenebis(oxy))bis-;UNII-7493SP153D;7493SP153D;4850-74-2;acetaldehyde diphenyl acetal;DIPHENOXYETHYLFORMAL;SCHEMBL542873;Q27266260

Chemical Property of 1,1-Diphenoxyethane

Chemical Property:

• XLogP3: 4.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 214.099379685
• Heavy Atom Count: 16
• Complexity: 161

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(OC1=CC=CC=C1)OC2=CC=CC=C2

Technology Process of 1,1-Diphenoxyethane

There total 10 articles about 1,1-Diphenoxyethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

vinyl phenyl ether (766-94-9) → bisphenoxyethane (4850-74-2) + 1,1-diphenoxycyclobutane

Guidance literature:

With tetrachlorophthalic anhydride; cadmium(II) sulphide; In dichloromethane; for 4h; Irradiation;

DOI:10.1021/ja00304a013

Reference yield:

1-Phenylethanol (98-85-1,13323-81-4) + phenylacetylene (536-74-3) → phenyl benzyl ketone (451-40-1) + bisphenoxyethane (4850-74-2)

Guidance literature:

With [Au(4,5-dichloro-1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)(CH₃CN)][BF₄]; In neat (no solvent); at 80 ℃;

DOI:10.1021/cs501976s

Reference yield:

phenoxyethyl bromide (589-10-6) → bisphenoxyethane (4850-74-2) + acetaldehyde (75-07-0,9002-91-9) + 2,3-diphenoxybutane + phenol (108-95-2,27073-41-2)

Guidance literature:

With magnesium; at 600 ℃; under 0.01 - 0.1 Torr; Further byproducts. Title compound not separated from byproducts.;

DOI:10.1039/b108663d

upstream raw materials:

vinyl phenyl ether

vinyl acetate

phenol

phenoxyethyl bromide

Downstream raw materials:

(hexan-2-yloxy)benzene

(1'R)-1-phenoxyethyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

(1'S)-1-phenoxyethyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

vinyl phenyl ether