[(Cyclobut-1-en-1-yl)oxy](trimethyl)silane

Base Information

Chemical Name:[(Cyclobut-1-en-1-yl)oxy](trimethyl)silane
CAS No.:54623-41-5
Molecular Formula:C7H14OSi
Molecular Weight:142.273
Hs Code.:
DSSTox Substance ID:DTXSID10504241
Nikkaji Number:J1.972.114K
Wikidata:Q82358588

Synonyms:54623-41-5;[(Cyclobut-1-en-1-yl)oxy](trimethyl)silane;SCHEMBL5264454;DTXSID10504241;(CYCLOBUT-1-EN-1-YLOXY)TRIMETHYLSILANE

Suppliers and Price of [(Cyclobut-1-en-1-yl)oxy](trimethyl)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
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Total 0 raw suppliers

Chemical Property of [(Cyclobut-1-en-1-yl)oxy](trimethyl)silane

Chemical Property:

Boiling Point:132.4±8.0 °C(Predicted)
PSA：9.23000
Density:0.88±0.1 g/cm3(Predicted)
LogP:2.51560
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:142.081391600
Heavy Atom Count:9
Complexity:132

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)OC1=CCC1

Technology Process of [(Cyclobut-1-en-1-yl)oxy](trimethyl)silane

There total 1 articles about [(Cyclobut-1-en-1-yl)oxy](trimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 4071-85-6
trimetylsilylketene

: 1191-95-3
cyclobutanone

: 107-46-0
Hexamethyldisiloxane

: 62012-20-8
3-(trimethylsilyl)cyclobutanone

: 54623-41-5
1-<(trimethylsilyl)oxy>cyclobutene

Guidance literature:: With water; mercury(II) iodide; Yield given. Multistep reaction;

Reference yield: 84.0%

: 54623-41-5
1-<(trimethylsilyl)oxy>cyclobutene

: 100-52-7
benzaldehyde

: (2R)-2-((R)-hydroxy(phenyl)methyl)cyclobutanone

Guidance literature:: 1-<(trimethylsilyl)oxy>cyclobutene; benzaldehyde; With C₈₄H₈₁F₁₇NO₄PS₂Si₂; In toluene; at -100 ℃; for 16h; Inert atmosphere; Sealed tube;

With hydrogenchloride; In tetrahydrofuran; water; toluene; at 20 ℃; for 0.5h; stereoselective reaction; Inert atmosphere; Sealed tube;
DOI:10.1021/jacs.5b04168

Reference yield:

: 54623-41-5
1-<(trimethylsilyl)oxy>cyclobutene

: 6630-33-7
ortho-bromobenzaldehyde

: (S)-(2-Bromo-phenyl)-(2-trimethylsilanyloxy-cyclobut-2-enyl)-methanol

: (R)-(2-Bromo-phenyl)-(2-trimethylsilanyloxy-cyclobut-2-enyl)-methanol

Guidance literature:: With barium(II) oxide; (1S,2R)-CrCl(OC₆H₂(C(CH₃)3)(OCOCH₃)CHNC₃H₄(O)C₆H₄); In dichloromethane; at 4 ℃; Title compound not separated from byproducts;
DOI:10.1002/anie.200351591