Benzyl[(4-methylphenyl)methyl]amine

Base Information

• Chemical Name: Benzyl[(4-methylphenyl)methyl]amine
• CAS No.: 55096-86-1
• Molecular Formula: C15H17N
• Molecular Weight: 211.307
• Hs Code.: 2921499090
• DSSTox Substance ID: DTXSID10373454
• Nikkaji Number: J875.795J
• Wikidata: Q82161628
• Mol file: 55096-86-1.mol

Synonyms:benzyl[(4-methylphenyl)methyl]amine;55096-86-1;Benzyl-(4-methylbenzyl)amine;N-Benzyl-1-(p-tolyl)methanamine;N-[(4-methylphenyl)methyl]-1-phenylmethanamine;(4-Methylbenzyl)benzylamine;Oprea1_270185;benzyl (4-methylbenzyl)amine;N-benzyl-1-p-tolylmethanamine;SCHEMBL7625869;benzyl-(4-methyl-benzyl)-amine;DTXSID10373454;n-benzyl-n-(4-methylbenzyl)amine;AKOS000225930;SB79506;CS-0246425;EN300-32616;Z57329041

Chemical Property of Benzyl[(4-methylphenyl)methyl]amine

Chemical Property:

• PSA: 12.03000
• LogP: 3.67570
• XLogP3: 3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 211.136099547
• Heavy Atom Count: 16
• Complexity: 176

Purity/Quality:

98%min ^*data from raw suppliers

benzyl[(4-methylphenyl)methyl]amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)CNCC2=CC=CC=C2

Technology Process of Benzyl[(4-methylphenyl)methyl]amine

There total 36 articles about Benzyl[(4-methylphenyl)methyl]amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

benzaldehyde (100-52-7) + para-methylbenzylamine (104-84-7) → benzyl(4-methylbenzyl)amine (55096-86-1)

Guidance literature:

With hydrogen; In water; at 130 ℃; for 20h; under 33753.4 Torr; Autoclave;

DOI:10.1039/c9sc04963k

Reference yield: 96.0%

para-methylbenzonitrile (104-85-8) + benzylamine (100-46-9) → benzyl(4-methylbenzyl)amine (55096-86-1)

Guidance literature:

With 1,3,2-oxazaborolidine-borane; copper(II) bis(trifluoromethanesulfonate); In water; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1021/acs.joc.1c02413

Reference yield: 92.0%

p-toluidine (106-49-0,12221-03-3) + benzyl alcohol (100-51-6,185532-71-2) → benzyl(4-methylbenzyl)amine (55096-86-1) + (4-Methyl-benzyl)-[1-phenyl-meth-(E)-ylidene]-amine

Guidance literature:

With C₂₆H₃₀N₂NiO₃; sodium hydroxide; In toluene; for 20h; Reflux; Molecular sieve; Inert atmosphere;

DOI:10.1021/acs.organomet.1c00552

upstream raw materials:

N-benzyl-p-tolylmethanimine

4-Methylbenzyl bromide

benzylamine

carbon dioxide

Downstream raw materials:

N-benzylidene-1-(p-tolyl)methanamine

N-benzyl-p-tolylmethanimine

4-methyl-benzaldehyde

benzaldehyde