Isobornyl chloride

Base Information

• Chemical Name: Isobornyl chloride
• CAS No.: 559-45-5
• Molecular Formula: C10H17Cl
• Molecular Weight: 172.698
• Mol file: 559-45-5.mol

Synonyms:

Chemical Property of Isobornyl chloride

Chemical Property:

• Melting Point: 158 °C
• Boiling Point: 207.5±0.0 °C(Predicted)
• PSA: 0.00000
• Density: 1.01±0.1 g/cm3(Predicted)
• LogP: 3.44000

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Isobornyl chloride

There total 60 articles about Isobornyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

camphene (79-92-5) + 3,3-dimethyl-allyl chloride (503-60-6) → bornyl chloride (464-41-5,559-45-5,6120-13-4,27720-69-0,30462-53-4,33602-15-2,73804-39-4,91547-96-5) + 4-methyl-1-(3',3'-dimethylbicyclo<2.2.1>hept-2-ylidene)pent-2-ene (116877-32-8) + (E)-isosantalene (63028-14-8) + 5-(1-chloro-1-methyl-ethyl)-2-methyl-7-(3',3'-dimethylbicyclo<2.2.1>hept-2-ylidene)hept-2-ene (116877-33-9,116948-00-6)

Guidance literature:

With zinc(II) chloride; In diethyl ether; dichloromethane; at -78 ℃; for 18h;

DOI:10.1016/S0040-4020(01)83451-7

Reference yield:

methylmagnesium bromide (75-16-1) → bornyl chloride (464-41-5,559-45-5,6120-13-4,27720-69-0,30462-53-4,33602-15-2,73804-39-4,91547-96-5) + 6endo,6'endo-dichloro-1,7,7,1',7',7'-hexamethyl-[2ξ,2'=x]binorbornyl

Guidance literature:

With diethyl ether; cobalt(II) chloride;

DOI:10.1021/ja01603a061

Reference yield:

→ bornyl chloride (464-41-5,559-45-5,6120-13-4,27720-69-0,30462-53-4,33602-15-2,73804-39-4,91547-96-5)

Guidance literature:

at 140 - 150 ℃;

upstream raw materials:

methanol

3-chloro-2.2.3-trimethyl-norbornane of uncertain configuration

Pinene

(+)-camphene

Downstream raw materials:

((1R)-isobornyl)-methyl ether

exo-2-Methoxy-1,7,7-trimethylbicyclo[2.2.1]heptane

2-endo-chloro-bornane

isobornyl acetate

Refernces

• 1、 Rahman, Azizur,Baeuml, Englbert,Klein, Herbert,Mayr, Herbert. "PRENYLATION OF CAMPHENE - A CARBOCATIONIC ROUTE TO ISOSANTALENE AND ITS DERIVATIVES". . p. 4119 - 4124. Retrieved 2007/10/02.