Methyl (2-chloro-4-sulfanylphenoxy)acetate

Base Information

Chemical Name:Methyl (2-chloro-4-sulfanylphenoxy)acetate
CAS No.:56077-49-7
Molecular Formula:C9H9ClO3S
Molecular Weight:232.688
Hs Code.:
DSSTox Substance ID:DTXSID20583108
Wikidata:Q82474627

Synonyms:56077-49-7;Methyl (2-chloro-4-sulfanylphenoxy)acetate;SCHEMBL3273629;DTXSID20583108

Suppliers and Price of Methyl (2-chloro-4-sulfanylphenoxy)acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl (2-chloro-4-sulfanylphenoxy)acetate

Chemical Property:

XLogP3:2.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:231.9960930
Heavy Atom Count:14
Complexity:201

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)COC1=C(C=C(C=C1)S)Cl

Technology Process of Methyl (2-chloro-4-sulfanylphenoxy)acetate

There total 5 articles about Methyl (2-chloro-4-sulfanylphenoxy)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 67-56-1
methanol

: 56077-58-8
(2-chloro-4-mercapto-phenoxy)-acetic acid

: 56077-49-7
methyl (2-chloro-4-mercapto-phenoxy)-acetate

Guidance literature:: With acetyl chloride; for 2h;
DOI:10.1021/jm061202u

Reference yield:

: 95-57-8
2-monochlorophenol

: 56077-49-7
methyl (2-chloro-4-mercapto-phenoxy)-acetate

Guidance literature:: Multi-step reaction with 4 steps

1.1: potassium carbonate / butan-2-one / 24 h / 100 °C

2.1: 76 percent / chlorosulfonic acid / CH₂Cl₂ / 1 h / 20 °C

3.1: red phosphorus; I₂; acetic acid / 24 h / Heating

3.2: H₂O / 1 h / Heating

4.1: 17 g / acetyl chloride / 2 h

With chlorosulfonic acid; phosphorus; iodine; potassium carbonate; acetic acid; acetyl chloride; In dichloromethane; butanone;
DOI:10.1021/jm061202u

Reference yield:

: 52094-97-0
ethyl 2-(2-chlorophenoxy)acetate

: 56077-49-7
methyl (2-chloro-4-mercapto-phenoxy)-acetate

Guidance literature:: Multi-step reaction with 3 steps

1.1: 76 percent / chlorosulfonic acid / CH₂Cl₂ / 1 h / 20 °C

2.1: red phosphorus; I₂; acetic acid / 24 h / Heating

2.2: H₂O / 1 h / Heating

3.1: 17 g / acetyl chloride / 2 h

With chlorosulfonic acid; phosphorus; iodine; acetic acid; acetyl chloride; In dichloromethane;
DOI:10.1021/jm061202u