Benzoic acid, thallium(1+) salt

Base Information

• Chemical Name: Benzoic acid, thallium(1+) salt
• CAS No.: 5630-31-9
• Molecular Formula: C7H6O2.Tl
• Molecular Weight: 325.499
• Mol file: 5630-31-9.mol

Synonyms:

Chemical Property of Benzoic acid, thallium(1+) salt

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoic acid, thallium(1+) salt

There total 2 articles about Benzoic acid, thallium(1+) salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

ethyl[bis(pentafluorophenyl)germyl]thallium(I) + dibenzoyl peroxide (94-36-0) → (C6F5)2Ge(C2H5)OCOC6H5 (85813-96-3) + thallium benzoate (5630-31-9)

Guidance literature:

In benzene; under Ar, benzene soln. of ethyl(bis(pentafluorophenyl)germyl)thallium(I) added to soln. of benzoyl peroxide in benzene, kept for 10 min at 20°C; org. layer decanted, benzene removed in vac., residue recrystd. from hexane, elem. anal.;

DOI:10.1016/S0022-328X(00)98573-5

Reference yield: 80.0%

thallium(I) acetate (563-68-8) + benzoic acid (65-85-0,8013-63-6) → thallium benzoate (5630-31-9)

Guidance literature:

In water; byproducts: CH3COOH; (inert atm.), Tl acetate and carboxylic acid dissolved in H2O; distilled, washed (acetone), recrystd.(acetone/H2O), elem. anal.;

DOI:10.1002/ejic.200300816

Reference yield: 97.0%

copper(l) iodide (7681-65-4) + N,N,N,N,-tetramethylethylenediamine (110-18-9) + sodium tetraphenyl borate (143-66-8) + thallium benzoate (5630-31-9) → [Cu2(tmen)2(μ-CO)(μ-PhCO2)](B(C6H5)4) (81770-59-4,75812-17-8)

Guidance literature:

With CO; In dichloromethane; byproducts: TlI, NaO2CC6H5; suspn. of CuI was stirred for 30 min under CO; tmed was added, stirringfor 20 min; addn. of TlOBz; stirring under CO for 30 min; filtration, addn. of NaBPh4 to filtrate over 10 min; react. for 30 min; filtration, evapn., washing with pentane; elem. anal.;

DOI:10.1021/om00072a012

upstream raw materials:

thallium(I) acetate

benzoic acid

dibenzoyl peroxide

Downstream raw materials:

2-iodo-1-phenylethyl benzoate

1-Benzoyloxy-1-phenyl-2-iodpropan

Benzoic trimethylacetic anhydride

benzoyl acetate