3,6-Dimethoxy-9H-carbazole

Base Information

• Chemical Name: 3,6-Dimethoxy-9H-carbazole
• CAS No.: 57103-01-2
• Molecular Formula: C14H13NO2
• Molecular Weight: 227.25900
• European Community (EC) Number: 834-909-6
• DSSTox Substance ID: DTXSID80349388
• Nikkaji Number: J3.320.600C
• Wikidata: Q27212893
• ChEMBL ID: CHEMBL1562810
• Mol file: 57103-01-2.mol

Synonyms:3,6-Dimethoxy-9H-carbazole;57103-01-2;3,6-dimethoxycarbazole;MFCD00626046;SMR000001088;Oprea1_346578;Oprea1_567958;MLS000029186;SCHEMBL2597652;CHEMBL1562810;DTXSID80349388;CHEBI:123213;HMS2376N10;AKOS000733280;DS-19180;SY234603;CS-0167938;D4833;FT-0701175;W15026;A900187;SR-01000508323;SR-01000508323-1;Q27212893

Chemical Property of 3,6-Dimethoxy-9H-carbazole

Chemical Property:

• Melting Point: 131-133 °C
• Boiling Point: 426.7±25.0 °C(Predicted)
• PKA: 17.26±0.30(Predicted)
• PSA: 34.25000
• Density: 1.235±0.06 g/cm3(Predicted)
• LogP: 3.33830
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 227.094628657
• Heavy Atom Count: 17
• Complexity: 245

Purity/Quality:

98%,99%, ^*data from raw suppliers

3,6-Dimethoxy-9H-carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC2=C(C=C1)NC3=C2C=C(C=C3)OC

Technology Process of 3,6-Dimethoxy-9H-carbazole

There total 10 articles about 3,6-Dimethoxy-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

3,6-dibromo-9H-carbazole (6825-20-3) + sodium methylate (124-41-4) → 3,6-di-methoxy-9H-carbazole (57103-01-2)

Guidance literature:

With copper(l) iodide; In N,N-dimethyl-formamide; for 8h; Reflux; Inert atmosphere;

DOI:10.1016/S1872-2067(15)61047-6

Reference yield: 85.0%

methanol (67-56-1) + 3,6-dibromo-9H-carbazole (6825-20-3) → 3,6-di-methoxy-9H-carbazole (57103-01-2)

Guidance literature:

methanol; With sodium; at 0 - 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

3,6-dibromo-9H-carbazole; With copper(l) iodide; In N,N-dimethyl-formamide; at 80 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1002/asia.201600538

Reference yield: 84.0%

5-methoxy-1-(4-methoxyphenyl)-1H-benzo[d][1,2,3]triazole → 3,6-di-methoxy-9H-carbazole (57103-01-2)

Guidance literature:

In acetonitrile; for 24h; UV-irradiation; Inert atmosphere;

DOI:10.1002/ejoc.201700300

upstream raw materials:

3,6-dibromo-9H-carbazole

sodium methylate

9H-carbazole

methanol

Refernces

• 1、 Han, Won-Sik,Kim, Seung-Hwan,Lee, Sohee,Lee, Sunhee,Lee, Yeeun,Lee, Yong Sup,Wang, Kang-Kyun,Yang, Kwang-Hwan. "Pyridazine–carbazole based fluorescent probes for volatile acid detection". . . Retrieved 2021.
• 2、 Lee, Kun-Mu,Yang, Jui-Yu,Lai, Ping-Sheng,Luo, Ke-Jyun,Yang, Ting-Yu,Liau, Kang-Ling,Abate, Seid Yimer,Lin, Yan-Duo. "A star-shaped cyclopentadithiophene-based dopant-free hole-transport material for high-performance perovskite solar cells". supporting information. p. 6444 - 6447. Retrieved 2021/07/02.
• 3、 Li, Ganggang,Li, Jiafang,Li, Kai,Liu, He,Liu, Zhiwen,Wang, Zhiming,Yang, Chuluo,Zhan, Qun,Zhang, Bing,Zhou, Changjiang. "A simple strategy to achieve efficient thermally activated delayed fluorescent emitters via enhancing electron donating ability of donors". . . Retrieved 2020/05/18.