Gallium, tris(2,4,6-trimethylphenyl)-

Base Information

• Chemical Name: Gallium, tris(2,4,6-trimethylphenyl)-
• CAS No.: 60607-12-7
• Molecular Formula: C27H33Ga
• Molecular Weight: 427.282
• Mol file: 60607-12-7.mol

Synonyms:

Chemical Property of Gallium, tris(2,4,6-trimethylphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Gallium, tris(2,4,6-trimethylphenyl)-

There total 2 articles about Gallium, tris(2,4,6-trimethylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.6%

2,4,6-trimethylphenyl bromide (576-83-0) + Gallium trichloride (13450-90-3) + magnesium (7439-95-4) → trimesitylgallium (60607-12-7)

Guidance literature:

In diethyl ether; inert atmosphere; addn. of MesMgBr (prepared from Mg and MesBr) to GaCl3 soln., refluxing (16 h); solvent removal (vac.), repeated extn. (pentane), recrystn. (pentane), sublimation (160-170°C, vac.); elem. anal.;

DOI:10.1021/om00140a010

Reference yield:

hexane (110-54-3) + (HC(CMeN(2,6-(i)Pr2C6H3))2)TiMe3 (956726-91-3) + [Mes2Ga(OH)]2-THF → (HC(CMeN(2,6-(i)Pr2C6H3))2)TiMe(μ-O)2TiMe(HC(CMeN(2,6-(i)Pr2C6H3))2)*n-hexane (956897-79-3) + trimesitylgallium (60607-12-7)

Guidance literature:

In toluene; under N2 atm. soln. Ti and Ga complexes in toluene was heated at 100°C for 14 h; soln. was filtered hot, volatiles were removed in vacuo, residue was dissolved in hexane, concd., and left at +2°C for 5 days;

DOI:10.1039/b710470g

Reference yield: 97.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + water (7732-18-5) + trimesitylgallium (60607-12-7) → (Mes2Ga(OH))2*THF

Guidance literature:

In tetrahydrofuran; water; (N2); warming from -30°C to room temp., stirring (24 h); evapn., recrystn. (THF); elem. anal.;

DOI:10.1021/ja953213a

upstream raw materials:

2,4,6-trimethylphenyl bromide

Gallium trichloride

magnesium

hexane

Downstream raw materials:

1,3,5-trimethyl-benzene

{(CO)3MoMes}GaMes₂

{(CO)3MoMes}2GaMes

{(CO)3CrMes}GaMes₂