Diiodoplatinum;triphenylphosphanium

Base Information

Chemical Name:Diiodoplatinum;triphenylphosphanium
CAS No.:23523-31-1
Molecular Formula:C₃₆H₃₀I₂P₂Pt
Molecular Weight:973.471
Hs Code.:
DSSTox Substance ID:DTXSID70422750
Mol file:23523-31-1.mol

Synonyms:NSC187650;23523-31-1;DTXSID70422750

Suppliers and Price of Diiodoplatinum;triphenylphosphanium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Diiodoplatinum;triphenylphosphanium

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:6
Exact Mass:974.97166
Heavy Atom Count:41
Complexity:204

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.I[Pt]I

Technology Process of Diiodoplatinum;triphenylphosphanium

There total 32 articles about Diiodoplatinum;triphenylphosphanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 10025-99-7
potassium tetrachloroplatinate(II)

: 603-35-0
triphenylphosphine

: 7681-11-0
potassium iodide

: 23523-31-1,35085-01-9,35085-00-8
diiodobis(triphenylphosphine)platinum(II)

Guidance literature:: In water; acetone; KI was added to aq. soln. K2PtCl4 and stirred for q5 min, soln. PPh3 in acetone was added and stirred at room temp. for 2 h; ppt. was filtered, washed with acetone and dried in vacuo - mixt. trans-and cis-isomers 4:1;
DOI:10.1039/b813125b

Reference yield: 88.0%

: 86526-00-3,173829-49-7,125994-41-4
PtI₂(PhCN)₂

: 603-35-0
triphenylphosphine

: 35085-00-8,23523-31-1,35085-01-9
trans-diiodobis(triphenylphosphane)platinum(II)

Guidance literature:: In benzene; PPh3 was added to suspn. Pt complex in benzene and refluxed for 4 h; react. mixt. was cooled, i-Pr2O was added; elem. anal.;
DOI:10.1039/b813125b

Reference yield: 80.0%

: 10199-34-5,14056-88-3,15604-36-1
cis-dichlorobis(triphenylphosphine)platinum(II)

: 35085-00-8,23523-31-1,35085-01-9
cis-diiodobis(triphenylphosphane)platinum(II)

Guidance literature:: With KI; In acetone; addn. of KI to suspn. of cis-(PtCl2(PPh3)2) in acetone, refluxed (10 h); evapn. to dryness, extn. with hot CHCl3, filtered, concn., pptn. by addn. of Et2O; elem. anal.;
DOI:10.1016/0022-328X(91)83106-E