1,1,1,3,3,3-Hexachloro-2-(trichlorosilyl)trisilane

Base Information

• Chemical Name: 1,1,1,3,3,3-Hexachloro-2-(trichlorosilyl)trisilane
• CAS No.: 62257-60-7
• Molecular Formula: Cl9HSi4
• Molecular Weight: 432.427
• European Community (EC) Number: 831-357-8
• Mol file: 62257-60-7.mol

Synonyms:62257-60-7;TRIS(TRICHLOROSILYL)SILANE;1,1,1,3,3,3-Hexachloro-2-(trichlorosilyl)trisilane;DTXSID40810302

Chemical Property of 1,1,1,3,3,3-Hexachloro-2-(trichlorosilyl)trisilane

Chemical Property:

• Boiling Point: 60-62°C / 0.2
• PSA: 0.00000
• LogP: 4.41460
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 430.621480
• Heavy Atom Count: 13
• Complexity: 134

Purity/Quality:

98%,99%, ^*data from raw suppliers

TRIS-(TRICHLOROSILYL)SILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Si]([Si](Cl)(Cl)Cl)([Si](Cl)(Cl)Cl)[Si](Cl)(Cl)Cl

Technology Process of 1,1,1,3,3,3-Hexachloro-2-(trichlorosilyl)trisilane

There total 2 articles about 1,1,1,3,3,3-Hexachloro-2-(trichlorosilyl)trisilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

hydrogenchloride (7647-01-0,15364-23-5) + tetrakis(trichlorosilyl)silane (50350-62-4) → 1,1,1,3,3,3-hexachloro-2-(trichlorosilyl)trisilane (62257-60-7)

Guidance literature:

With tetrachlorosilane; In diethyl ether; at 18 - 20 ℃; for 0.666667h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1002/anie.201710416

Reference yield: 70.0%

tetrakis(trichlorosilyl)silane (50350-62-4) → 1,1,1,3,3,3-hexachloro-2-(trichlorosilyl)trisilane (62257-60-7)

Guidance literature:

tetrakis(trichlorosilyl)silane; In tetrachlorosilane; at 40 - 50 ℃;

With hydrogenchloride; In tetrachlorosilane; diethyl ether; at 15 - 25 ℃; for 4h;

Reference yield:

1,1,1,3,3,3-hexachloro-2-(trichlorosilyl)trisilane (62257-60-7) → 1,1,1,2,2-pentachlorodisilane (31411-98-0) + trichlorosilane (10025-78-2)

Guidance literature:

With hydrogenchloride; lithium aluminium tetrahydride; In benzene; introduction of HCl gas into a soln. of HSi(SiCl3)3 and a very few trimethylamine, at room temp.; detection by Raman and (1)H-NMR; Kinetics;

DOI:10.1007/BF00938714

upstream raw materials:

tetrakis(trichlorosilyl)silane

hydrogenchloride

Downstream raw materials:

1,1,1,2,2-pentachlorodisilane

trichlorosilane

Refernces

• 1、 Arkles, Barry,Pan, Youlin,Jove, Fernando,Goff, Jonathan,Kaloyeros, Alain. "Synthesis and Exploratory Deposition Studies of Isotetrasilane and Reactive Intermediates for Epitaxial Silicon". . . Retrieved 2019.