Stannane, bis[2,6-bis(trifluoromethyl)phenyl]dichloro-

Base Information

Chemical Name:Stannane, bis[2,6-bis(trifluoromethyl)phenyl]dichloro-
CAS No.:650583-85-0
Molecular Formula:C₁₆H₆Cl₂F₁₂Sn
Molecular Weight:615.82
Hs Code.:
DSSTox Substance ID:DTXSID00477031

Synonyms:Stannane, bis[2,6-bis(trifluoromethyl)phenyl]dichloro-;650583-85-0;DTXSID00477031

Suppliers and Price of Stannane, bis[2,6-bis(trifluoromethyl)phenyl]dichloro-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Stannane, bis[2,6-bis(trifluoromethyl)phenyl]dichloro-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:12
Rotatable Bond Count:2
Exact Mass:615.867696
Heavy Atom Count:31
Complexity:528

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=C(C(=C1)C(F)(F)F)[Sn](C2=C(C=CC=C2C(F)(F)F)C(F)(F)F)(Cl)Cl)C(F)(F)F

Technology Process of Stannane, bis[2,6-bis(trifluoromethyl)phenyl]dichloro-

There total 2 articles about Stannane, bis[2,6-bis(trifluoromethyl)phenyl]dichloro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 136664-85-2
2,4-(CF₃)2C₆H₃Li

: 7646-78-8
tin(IV) chloride

: 80426-23-9
(2,6-bis(trifluoromethyl)-phenyl)lithium

: 650583-84-9
bis[2,4-bis(trifluoromethyl)phenyl]dichlorostannane

: 650583-85-0
bis[2,6-bis(trifluoromethyl)phenyl]dichlorostannane

Guidance literature:: In diethyl ether; hexane; byproducts: LiCl; (N2); Schlenk technique or glovebox; soln. of mixt. of Li compd. (2 equiv.) in Et2O was added dropwise to soln. of SnCl4 (1 equiv.) in hexane atroom temp. and stirred for 4 h; filtered; solvents removed (vac.); oily residue filtered; filtered-off residue washed (pentane; CH2Cl2); dried (vac.); recrystd. (pentane and Et2O); elem. anal.;
DOI:10.1039/b302544f

Reference yield:

: 402-31-3
1,3-bis(trifluoromethyl)benzene

: 7646-78-8
tin(IV) chloride

: 650583-84-9
bis[2,4-bis(trifluoromethyl)phenyl]dichlorostannane

: 650583-85-0
bis[2,6-bis(trifluoromethyl)phenyl]dichlorostannane

Guidance literature:: 1,3-bis(trifluoromethyl)benzene; With n-butyllithium; In diethyl ether; at -78 ℃;

tin(IV) chloride; In hexane; at -78 ℃;
DOI:10.1002/hlca.201200389