Borane, phenylbis(2,4,6-trimethylphenyl)-

Base Information

Chemical Name:Borane, phenylbis(2,4,6-trimethylphenyl)-
CAS No.:65881-97-2
Molecular Formula:C24H27B
Molecular Weight:326.289
Hs Code.:
DSSTox Substance ID:DTXSID50505873
Nikkaji Number:J731.595C
Wikidata:Q82361269

Synonyms:Dimesitylphenylborane;Borane, phenylbis(2,4,6-trimethylphenyl)-;phenyldimesitylborane;65881-97-2;Dimesityl-phenyl-borane;DTXSID50505873;Phenylbis(2,4,6-trimethylphenyl)borane;phenyl[bis(2,4,6-trimethylphenyl)]borane

Suppliers and Price of Borane, phenylbis(2,4,6-trimethylphenyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Borane, phenylbis(2,4,6-trimethylphenyl)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:326.2205810
Heavy Atom Count:25
Complexity:358

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=CC=CC=C1)(C2=C(C=C(C=C2C)C)C)C3=C(C=C(C=C3C)C)C

Technology Process of Borane, phenylbis(2,4,6-trimethylphenyl)-

There total 13 articles about Borane, phenylbis(2,4,6-trimethylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: [mesitylcopper]5*toluene

: 873-51-8
phenylborondichloride

: 65881-97-2
dimesityl(phenyl)borane

: 612844-48-1
mesitylphenylchloroborane

Guidance literature:: In toluene; under N2; soln. of PhBCl2 (1.05 equiv) in toluene added dropwise to soln. of (CuMes)5*toluene in toluene at -78 °C; mixt. allowed to slowly warm to room temp. and subsequently kept at 60 °C for 2 h; after filtration all volatiles removed under high vac.; crude product purified by distn.;
DOI:10.1016/S0022-328X(03)00588-6

Reference yield: 74.0%

: 436-59-9
dimesitylfluoroborane

: 591-51-5
phenyllithium

: 65881-97-2
dimesityl(phenyl)borane

Guidance literature:: In diethyl ether; (N2); fluorodimesitylborane/ether added dropwise to phenyllithium/ether, refluxed for 2 h; poured into cold H2O at room temp., org. layer sepd., dried (MgSO4), evapd., recrystd. (EtOAc);
DOI:10.1016/S0022-328X(00)88968-8

Reference yield: 72.0%

: 108-86-1,52753-63-6
bromobenzene

: 440361-72-8
(diphenylmethylsilyl)dimesitylborane

: 65881-97-2
dimesityl(phenyl)borane

: 791-29-7
methyltriphenylsilane

Guidance literature:: (diphenylmethylsilyl)dimesitylborane; With sodium t-butanolate; In 1,4-dioxane; hexane; at 50 ℃; for 0.0833333h; Inert atmosphere;

bromobenzene; In 1,4-dioxane; hexane; at 50 ℃; for 24h; Inert atmosphere;
DOI:10.1002/chem.201604021