791-29-7Relevant articles and documents
Crystal structures of the chiral diamine (R,R)-TMCDA with the commonly used alkyllithium bases methyllithium, iso-propyllithium, and sec-butyllithium
Strohmann, Carsten,Gessner, Viktoria H.
, p. 8952 - 8953 (2007)
(R,R)-N,N,N′,N′-Tetramethyl-1,2-diaminocyclohexane [(R,R)-TMCDA] coordinated alkyllithiums crystallize as dimeric [MeLi·(R,R)-TMCDA]2 and [i-PrLi·(R,R)-TMCDA]2 and monomeric s-BuLi·(R,R)-TMCDA. s-BuLi·(R,R)-TMCDA is the first structu
Nickel-Catalyzed Decarbonylation of Acylsilanes
Ito, Yuri,Kodama, Takuya,Nakatani, Syun,Sakurai, Shun,Tobisu, Mamoru
, p. 7588 - 7594 (2020/06/27)
Nickel-catalyzed decarbonylation of acylsilanes is developed. In sharp contrast to cross-coupling reactions of acylsilanes, in which the silyl group serves as a leaving group, the silyl group is retained in the product in this decarbonylation reaction. Although the strong binding of the dissociated CO to the nickel center frequently hinders catalyst turnover in nickel-mediated decarbonylative reactions, this reaction can be catalyzed by nickel complexes bearing a CO ligand.
Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes
Nagata, Tatsuki,Inoue, Takeru,Lin, Xianjin,Ishimoto, Shinya,Nakamichi, Seiya,Oka, Hideo,Kondo, Ryota,Suzuki, Takeyuki,Obora, Yasushi
, p. 17425 - 17431 (2019/06/24)
N,N-Dimethylformamide-stabilised Pd nanocluster (NC) catalysed cross-coupling reactions of hydrosilane/disilane have been investigated. In this reaction, the coupling reaction proceeds without ligands with low catalyst loading. N,N-Dimethylacetamide is a crucial solvent in these reactions. The solvent effect was considered by various techniques, such as transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The Pd NCs can be recycled five times under both hydrosilane and disilane reaction conditions.
