Silane, trimethyl(4-methylbenzoyl)-

Base Information

Chemical Name:Silane, trimethyl(4-methylbenzoyl)-
CAS No.:68185-94-4
Molecular Formula:C11H16OSi
Molecular Weight:192.333
Hs Code.:
DSSTox Substance ID:DTXSID10392721
Nikkaji Number:J805.569F
Wikidata:Q82191099

Synonyms:Silane, trimethyl(4-methylbenzoyl)-;4-Methylbenzoyltrimethylsilane;68185-94-4;(4-methylbenzoyl)trimethylsilane;DTXSID10392721;p-Tolyl-trimethylsilanyl-methanone

Suppliers and Price of Silane, trimethyl(4-methylbenzoyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Silane, trimethyl(4-methylbenzoyl)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:192.097041664
Heavy Atom Count:13
Complexity:185

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)C(=O)[Si](C)(C)C

Technology Process of Silane, trimethyl(4-methylbenzoyl)-

There total 7 articles about Silane, trimethyl(4-methylbenzoyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1450-14-2
1,1,1,2,2,2-hexamethyldisilane

: 874-60-2
4-methyl-benzoyl chloride

: 68185-94-4
trimethyl-4-methylbenzoylsilane

Guidance literature:: bis(η3-allyl-μ-chloropalladium(II)); triethyl phosphite; at 110 ℃; for 4.8h;
DOI:10.1016/S0040-4039(00)77777-X

Reference yield:

: 1450-14-2
1,1,1,2,2,2-hexamethyldisilane

: 201230-82-2
carbon monoxide

: 624-31-7
4-tolyl iodide

: 68185-94-4
trimethyl-4-methylbenzoylsilane

Guidance literature:: With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; triphenyl-arsane; In 1,4-dioxane; at 110 ℃; for 16h; under 7500.75 Torr; Autoclave;
DOI:10.1016/j.tetlet.2011.11.104

Reference yield:

: 56637-44-6
2-(4-methylphenyl)-1,3-dithiane

: 68185-94-4
trimethyl-4-methylbenzoylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran / 2 h / -78 °C / Inert atmosphere

1.2: 1 h / -78 - 20 °C / Inert atmosphere

2.1: mercury dichloride; mercury(II) oxide / methanol; water / 3 h / Inert atmosphere; Reflux

With n-butyllithium; mercury dichloride; mercury(II) oxide; In tetrahydrofuran; methanol; water;
DOI:10.1021/jacs.7b05165