Trisilane, 1,1,1,3,3,3-hexamethyl-2,2-bis(2,4,6-trimethylphenyl)-

Base Information

• Chemical Name: Trisilane, 1,1,1,3,3,3-hexamethyl-2,2-bis(2,4,6-trimethylphenyl)-
• CAS No.: 79184-72-8
• Molecular Formula: C24H40Si3
• Molecular Weight: 412.838
• DSSTox Substance ID: DTXSID40473916
• Nikkaji Number: J670.818H
• Wikidata: Q82303599

Synonyms:79184-72-8;Trisilane, 1,1,1,3,3,3-hexamethyl-2,2-bis(2,4,6-trimethylphenyl)-;2,2-dimesitylhexamethyltrisilane;DTXSID40473916

Chemical Property of Trisilane, 1,1,1,3,3,3-hexamethyl-2,2-bis(2,4,6-trimethylphenyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 412.24378088
• Heavy Atom Count: 27
• Complexity: 431

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=C(C(=C1)C)[Si](C2=C(C=C(C=C2C)C)C)([Si](C)(C)C)[Si](C)(C)C)C

Technology Process of Trisilane, 1,1,1,3,3,3-hexamethyl-2,2-bis(2,4,6-trimethylphenyl)-

There total 1 articles about Trisilane, 1,1,1,3,3,3-hexamethyl-2,2-bis(2,4,6-trimethylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

chloro-trimethyl-silane (75-77-4) + dichloro(dimesityl)silane (5599-27-9) → 2,2-dimesitylhexamethyltrisilane (79184-72-8)

Guidance literature:

With lithium perchlorate; In tetrahydrofuran; Ambient temperature; Mg cathode and anode, undivided cell, 5F/mol;

DOI:10.1016/S0040-4039(97)00987-8

Reference yield: 100.0%

[Pt(PiPr3)3] (60648-72-8) + 2,2-dimesitylhexamethyltrisilane (79184-72-8) → (i-Pr3P)2Pt=Si(2,4,6-trimethylphenyl)2

Guidance literature:

In benzene-d6; byproducts: Me3SiSiMe3; photolysis;

DOI:10.1021/ja981882t

Reference yield: 90.0%

2,2-dimesitylhexamethyltrisilane (79184-72-8) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → 3,4-dimethyl-1,1-bis(2,4,6-trimethylphenyl)-silacyclopent-3-ene (109853-00-1) + 1,1-dimesityl-2-methyl-2-isopropenylsilirane (133850-17-6)

Guidance literature:

In cyclohexane; for 6h; Ambient temperature; Irradiation;

DOI:10.1021/ja00011a033

upstream raw materials:

chloro-trimethyl-silane

dichloro(dimesityl)silane

Downstream raw materials:

1,1,1,2,2,2-hexamethyldisilane

1-butylene

styrene

(1-methylprop-2-enyl)dimesitylsilane

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