(Dichlorophosphinyl)phosphorimidic trichloride

Base Information

• Chemical Name: (Dichlorophosphinyl)phosphorimidic trichloride
• CAS No.: 13966-08-0
• Molecular Formula: Cl5N O P2
• Molecular Weight: 269.219
• DSSTox Substance ID: DTXSID10472416
• Nikkaji Number: J1.417.738H
• Wikidata: Q82301348
• Mol file: 13966-08-0.mol

Synonyms:13966-08-0;(Dichlorophosphinyl)phosphorimidic trichloride;DTXSID10472416;dichlorophosphinylphosphorimidic trichloride;N-(Dichlorophosphoryl)phosphorimidic trichloride

Chemical Property of (Dichlorophosphinyl)phosphorimidic trichloride

Chemical Property:

• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 268.786826
• Heavy Atom Count: 9
• Complexity: 177

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N(=P(Cl)(Cl)Cl)P(=O)(Cl)Cl

Technology Process of (Dichlorophosphinyl)phosphorimidic trichloride

There total 15 articles about (Dichlorophosphinyl)phosphorimidic trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

phosphorus pentachloride (10026-13-8,874483-75-7) + phosphoramidic acid (14700-20-0,2817-45-0) → hydrogenchloride (7647-01-0,15364-23-5) + dichlorophosphinylphosphorimidic trichloride (13966-08-0) + trichlorophosphate (10025-87-3,12599-09-6,63736-95-8,39380-77-3)

Guidance literature:

In further solvent(s); heating a suspension of PO(OH)2NH2 in tetrachlorethane with PCl4 on refluxing under exclusion of H2O for 4 h;; filtration of insol. products; continous removal of HCl with stream of dry air; expelling POCl3 and solvent at 90 °C and 14 Torr; solidification in high vac. at 55-58 °C;;

Reference yield:

bis(trichlorophosphine)iminium hexachlorophosphate (18828-06-3) → thionyl chloride (7719-09-7) + dichlorophosphinylphosphorimidic trichloride (13966-08-0) + trichlorophosphate (10025-87-3,12599-09-6,63736-95-8,39380-77-3)

Guidance literature:

With SO₂; In not given; react. with SO2;;

Reference yield:

bis(trichlorophosphine)iminium hexachlorophosphate (18828-06-3) → dichlorophosphinylphosphorimidic trichloride (13966-08-0) + trichlorophosphate (10025-87-3,12599-09-6,63736-95-8,39380-77-3)

Guidance literature:

With methanol; In nitromethane; byproducts: CH3Cl, HCl; addn. of methanol in nitromethane to suspn. of (Cl3PNPCl3)PCl6 in nitromethane (molar ratio 2:1) dropwise during 1 h at ambient temp.; various product ratio for various conditions; not isolated; (31)P-NMR spectroscopic monitoring;

upstream raw materials:

phosphorus pentachloride

phosphoramide

2,4-dichloro-1,3-bis(dichlorophosphoryl)-2,4-dioxocyclodiphosph(V)azane

bis(trichlorophosphine)iminium hexachlorophosphate

Downstream raw materials:

trichlorophosphate

tetrasodium [(17)O]imidodiphosphate decahydrate

hydrogenchloride

diamidophosphoric acid