bis(trichlorophosphine)iminium hexachlorophosphate

Base Information

• Chemical Name: bis(trichlorophosphine)iminium hexachlorophosphate
• CAS No.: 18828-06-3
• Molecular Formula: Cl₆NP₂*Cl₆P
• Molecular Weight: 532.364
• Mol file: 18828-06-3.mol

Synonyms:bis(trichlorophosphine)iminium hexachlorophosphate

Chemical Property of bis(trichlorophosphine)iminium hexachlorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(trichlorophosphine)iminium hexachlorophosphate

There total 1 articles about bis(trichlorophosphine)iminium hexachlorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

ammonium sulfate + phosphorus pentachloride (10026-13-8,874483-75-7) → bis(trichlorophosphine)iminium hexachlorophosphate (18828-06-3) + trichlorophosphate (10025-87-3,12599-09-6,63736-95-8,39380-77-3)

Guidance literature:

In further solvent(s); byproducts: SO2, Cl2, HCl; refluxing PCl5 and (NH4)2SO4 in 1,1,2,2-tetrachloroethane for 12 h; cooling, washing with CCl4 or petroleum ether, elem. anal.;

Reference yield: 89.0%

bis(trichlorophosphine)iminium hexachlorophosphate (18828-06-3) + molybdenum(V) chloride (10241-05-1) → bis(trichlorophosphine)iminium hexachloromolybdate(V) (116591-43-6) + phosphorus pentachloride (10026-13-8,874483-75-7)

Guidance literature:

In not given; exclusion of moisture, stirred for 12 h at room temp.; filtered, dissolved in CH2Cl2, pptd. with CCl4, filtered, washed with CCl4, dried in vac.; elem. anal.;

Reference yield:

bis(trichlorophosphine)iminium hexachlorophosphate (18828-06-3) → thionyl chloride (7719-09-7) + dichlorophosphinylphosphorimidic trichloride (13966-08-0) + trichlorophosphate (10025-87-3,12599-09-6,63736-95-8,39380-77-3)

Guidance literature:

With SO₂; In not given; react. with SO2;;

upstream raw materials:

phosphorus pentachloride

Downstream raw materials:

thionyl chloride

dichlorophosphinylphosphorimidic trichloride

trichlorophosphate

imido-bis(phosphoryldichloride)