Benzenemethanol, 4-methoxy-a-methyl-, 3,5-dinitrobenzoate

Base Information

• Chemical Name: Benzenemethanol, 4-methoxy-a-methyl-, 3,5-dinitrobenzoate
• CAS No.: 88563-47-7
• Molecular Formula: C16H14N2O7
• Molecular Weight: 346.296
• Mol file: 88563-47-7.mol

Synonyms:

Chemical Property of Benzenemethanol, 4-methoxy-a-methyl-, 3,5-dinitrobenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenemethanol, 4-methoxy-a-methyl-, 3,5-dinitrobenzoate

There total 1 articles about Benzenemethanol, 4-methoxy-a-methyl-, 3,5-dinitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

rac-1-(4-methoxyphenyl)-ethanol (3319-15-1) + 3,5-dinitrobenoyl chloride (99-33-2) → 1-(4-methoxyphenyl)ethyl 3,5-dinitrobenzoate (88563-47-7)

Guidance literature:

With pyridine; at 20 ℃; Inert atmosphere; Cooling with ice;

DOI:10.1246/bcsj.20110230

Reference yield:

1-(4-methoxyphenyl)ethyl 3,5-dinitrobenzoate (88563-47-7) → rac-1-(4-methoxyphenyl)-ethanol (3319-15-1) + 1-(1-azidoethyl)-4-methoxybenzene (91633-30-6)

Guidance literature:

With sodium azide; sodium acetate; In water; for 20h; Title compound not separated from byproducts; Ambient temperature;

DOI:10.1021/jo00074a036

Reference yield:

formic acid (64-18-6) + 2,2,2-trifluoroethanol (75-89-8) + 1-(4-methoxyphenyl)ethyl 3,5-dinitrobenzoate (88563-47-7) → rac-1-(4-methoxyphenyl)-ethanol (3319-15-1) + 1-(4-methoxyphenyl)ethyl trifluoroethyl ether (94670-31-2) + 1-(4-methoxyphenyl)ethyl formate

Guidance literature:

With sodium perchlorate; water; at 22 ℃; Product distribution;

DOI:10.1021/ja00317a032

upstream raw materials:

rac-1-(4-methoxyphenyl)-ethanol

3,5-dinitrobenoyl chloride

Downstream raw materials:

rac-1-(4-methoxyphenyl)-ethanol

1-methoxy-4-(1-methoxy-ethyl)-benzene

1-(4-methoxyphenyl)ethyl trifluoroethyl ether

1-(p-methoxyphenyl)ethyl acetate

Refernces