(propan-2-ylselanyl)benzene

Base Information

• Chemical Name: (propan-2-ylselanyl)benzene
• CAS No.: 22233-89-2
• Molecular Formula: C9H12 Se
• Molecular Weight: 199.154
• Hs Code.: 2931900090
• Mol file: 22233-89-2.mol

Synonyms:Selenide,isopropyl phenyl (8CI); Isopropyl phenyl selenide

Chemical Property of (propan-2-ylselanyl)benzene

Chemical Property:

• Vapor Pressure: 0.132mmHg at 25°C
• Boiling Point: 225.1°Cat760mmHg
• Flash Point: 89.9°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.84440

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (propan-2-ylselanyl)benzene

There total 13 articles about (propan-2-ylselanyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diphenyl diselenide (1666-13-3) + isopropyl bromide (75-26-3) → (phenylseleno)-2-propane (22233-89-2)

Guidance literature:

With sodium tetrahydroborate; In 1,2-dimethoxyethane; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1016/j.tetasy.2009.11.004

Reference yield: 100.0%

isopropylmercury(II) chloride (30615-19-1) → (phenylseleno)-2-propane (22233-89-2)

Guidance literature:

With diphenyl diselenide; In benzene; byproducts: PhSeHgCl; Irradiation (UV/VIS); nitrogen atmosphere; mercurial and PhSeSePh in deoxygenated solvent irradiated (275-W sunlamp, 35-40 °C, 6h);; filtration; solvent removed (vacuum); (CH3)2CHSePh analysed by (1)H NMR, GLC and GCMS;;

DOI:10.1021/ja00219a030

Reference yield: 86.0%

2-iodo-propane (75-30-9) + diphenyl diselenide (1666-13-3) → (phenylseleno)-2-propane (22233-89-2)

Guidance literature:

With sodium tetrahydroborate; In ethanol; Heating;

DOI:10.1021/jo00160a034

upstream raw materials:

isopropyl chloride

diphenyl diselenide

2-iodo-propane

isopropylmercury(II) chloride

Downstream raw materials:

2-methyl-1-phenylprop-2-en-1-one

2,3-Dimethyl-2-phenylseleno-5-phenyl-3-pentanol

1-Isopropenyl-1-cyclohexanol

2-methyl-1-phenylprop-2-en-1-ol