1-hexylcyclohexene

Base Information

• Chemical Name: 1-hexylcyclohexene
• CAS No.: 3964-66-7
• Molecular Formula: C12H22
• Molecular Weight: 166.3031
• Mol file: 3964-66-7.mol

Synonyms:1-hexyl-1-hexene;1-hexyl-cyclohexene;1-Hexyl-1-cyclohexene;1-n-hexylcyclohexene;Cyclohexene,1-hexyl;1-hexylcyclohex-1-ene;1-Hexyl-cyclohexen;

Chemical Property of 1-hexylcyclohexene

Chemical Property:

• Vapor Pressure: 0.138mmHg at 25°C
• Boiling Point: 224.2°Cat760mmHg
• Flash Point: 82.9°C
• PSA: 0.00000
• Density: 0.825g/cm³
• LogP: 4.45720

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-hexylcyclohexene

There total 8 articles about 1-hexylcyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

n-hexylmagnesium bromide (3761-92-0) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → 1-hexylcyclohex-1-ene (3964-66-7)

Guidance literature:

n-hexylmagnesium bromide; cyclohexanone; In diethyl ether; for 1h; Heating;

With iodine; In toluene; for 3h; Heating;

DOI:10.1007/s11178-005-0225-8

Reference yield: 79.0%

cyclohexene (110-83-8) + hexan-1-ol (111-27-3) → 1-hexylcyclohex-1-ene (3964-66-7)

Guidance literature:

With [(C₆H₆)(PCy₃)(CO)RuH]⁺*BF₄^?; In chlorobenzene; at 90 ℃; for 6h; Schlenk tube;

DOI:10.1126/science.1208839

Reference yield: 76.0%

n-hexylmagnesium bromide (3761-92-0) + (1-cyclohexenyl)bis(2-hydroxyphenyl)phosphinate (108803-39-0) → 1-hexylcyclohex-1-ene (3964-66-7)

Guidance literature:

With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; In tetrahydrofuran; for 0.5h; Inert atmosphere; Reflux;

DOI:10.1002/anie.201202818

upstream raw materials:

n-hexylmagnesium bromide

cyclohexanone

1-hexylcyclohexanol

1-bromo-hexane

Downstream raw materials:

trans-2-hexylcyclohexanol

cis-2-hexylcyclohexanol

1-benzenesulfonyl-dodecan-6-one