42604-09-1

Basic information

• Product Name: Cyclohexane, (methoxymethoxy)-
• CAS NO: 42604-09-1
• Molecular Formula: C8H16O2
• Molecular Weight: 144.214
• Mol File: 42604-09-1.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Cyclohexane, (methoxymethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, (methoxymethoxy)-(42604-09-1)
• EPA Substance Registry System: Cyclohexane, (methoxymethoxy)-(42604-09-1)

Safety Data

• Hazardous Substances Data: 42604-09-1(Hazardous Substances Data)

Upstream product

• 3587-62-0 chloromethyl cyclohexyl ether 
• 124-41-4 sodium methylate 
• 109-87-5 Dimethoxymethane 
• 1453-21-0 dicyclohexyloxymethane 
• 13057-17-5 bromethyl methyl ether 
• 108-93-0 cyclohexanol 
• 1327238-96-9 N-(cyclohexyloxymethoxy)-N-methylacetamide 
• 89727-03-7 O-(methoxymethyl)-1-(tri-n-butylstannyl)cyclohexanol 
• 107-30-2 chloromethyl methyl ether 
• 71995-54-5 2-(cyclohexyloxy)acetic acid 
• 109-72-8 n-butyllithium 

Downstream Products

• 108-93-0 cyclohexanol 
• 16224-09-2 benzyl cyclohexyl ether 
• 1327238-96-9 N-(cyclohexyloxymethoxy)-N-methylacetamide 
• 1327239-80-4 C₁₄H₂₀O 
• 1327239-01-9 (E)-(undec-2-enyloxy)cyclohexane 
• 1327239-10-0 1-fluoro-3-(cyclohexyloxymethyl)benzene 
• 1327239-11-1 1-((cyclohexyloxy)methyl)-2-methylbenzene 
• 1327239-15-5 1-(4-(cyclohexyloxymethyl)phenyl)ethanone 
• 1152517-74-2 4-[(cyclohexyloxy)methyl]benzoic acid methyl ester 
• 1327239-17-7 2-(cyclohexyloxymethyl)thiophene 
• 1327239-18-8 2-(cyclohexyloxymethyl)furan 
• 1327238-99-2 (3-(cyclohexyloxy)prop-1-ynyl)benzene 
• 1327239-04-2 2-(cyclohexyloxymethyl)benzo[b]thiophene 
• 1224436-10-5 1-bromo-3-(cyclohexyloxymethyl)benzene 

Relevant articles and documents

Polyfluoroaryl substituted alkane and preparation method thereof

The invention discloses polyfluoroaryl substituted alkane and a preparation method thereof, and belongs to the field of organic synthesis. The invention solves the problem that the existing synthesis of polyfluoroaryl substituted alkane needs metal catalysis, high temperature, no water, no oxygen and other harsh reaction conditions. The structural general formula of the polyfluoroaryl substituted alkane is shown in the specification. The method comprises the following steps of: adding polyfluorinated aromatic hydrocarbon, MOM protected alcohol, an Ir(ppy)3 photocatalyst, anhydrous potassium carbonate and ethyl 2-mercaptopropionate into an organic solvent at room temperature, uniformly mixing, carrying out illumination reaction, removing the solvent through reduced pressure distillation, and carrying out silica gel column chromatography separation and purification to obtain the polyfluoroaryl substituted alkane.

P4VPy–CuO nanoparticles as a novel and reusable catalyst: application at the protection of alcohols, phenols and amines

P4VPy–CuO nanoparticles were synthesized using ultrasound irradiations. Relevant properties of the synthesized nanoparticles were investigated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and Fourier transform infrared spectroscopy. After identification, the prepared reagent was used for the promotion of different types of protection reactions of alcohols, phenols and amines. Easy workup, short reaction times, excellent yields, relatively low cost and reusability of the catalyst are the striking features of the reported methods.

Highly efficient and selective methoxymethylation of alcohols and phenols catalyzed by reusable ZrO(OTf)2 under solvent-free conditions

Different primary, secondary, and tertiary alcohols were efficiently converted to their corresponding methoxymethyl ethers with formaldehyde dimethyl acetal in the presence of catalytic amounts of ZrO(OTf)2 at room temperature. Phenols were als