Benzeneselenyl chloride, 2-[(1S)-1-(methylthio)ethyl]-

Base Information

• Chemical Name: Benzeneselenyl chloride, 2-[(1S)-1-(methylthio)ethyl]-
• CAS No.: 919081-09-7
• Molecular Formula: C9H11ClSSe
• Molecular Weight: 265.665
• Mol file: 919081-09-7.mol

Synonyms:

Chemical Property of Benzeneselenyl chloride, 2-[(1S)-1-(methylthio)ethyl]-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzeneselenyl chloride, 2-[(1S)-1-(methylthio)ethyl]-

There total 2 articles about Benzeneselenyl chloride, 2-[(1S)-1-(methylthio)ethyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

C9H12SSe2 → 2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl chloride (919081-09-7)

Guidance literature:

With sulfuryl dichloride; In diethyl ether; at 0 ℃; for 0.5h;

DOI:10.1002/ejoc.200600517

Reference yield:

bis-2-[(1S)-1-(methylsulfanyl)ethyl]phenyl diselenide (278790-74-2) → 2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl chloride (919081-09-7)

Guidance literature:

With sulfuryl dichloride; In diethyl ether;

DOI:10.1055/s-0028-1087936

Reference yield: 65.0%

2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl chloride (919081-09-7) + methanol (67-56-1) + 3-phenyl-propenal (104-55-2) → C21H28O3SSe (1158732-07-0) + C21H28O3SSe + C21H28O3SSe + C21H28O3SSe

Guidance literature:

With magnesium sulfate; In dichloromethane; at 0 ℃; for 240h; enantioselective reaction;

DOI:10.1055/s-0028-1087936

upstream raw materials:

bis-2-[(1S)-1-(methylsulfanyl)ethyl]phenyl diselenide

Downstream raw materials:

(1R)-2-{2-[(1S)-1-(methylthio)ethyl]phenylselenenyl}-1-phenylethanol

C₂₅H₃₀O₃SSe

C₂₁H₂₇ClO₃SSe