4-methyl-N-[methyl(phenyl)-lambda~4~-sulfanylidene]benzenesulfonamide

Base Information

Chemical Name:4-methyl-N-[methyl(phenyl)-lambda~4~-sulfanylidene]benzenesulfonamide
CAS No.:10330-22-0
Molecular Formula:C₁₄H₁₅NO₂S₂
Molecular Weight:293.411
Hs Code.:
NSC Number:72486
Mol file:10330-22-0.mol

Synonyms:10330-22-0;4-methyl-N-[methyl(phenyl)-lambda~4~-sulfanylidene]benzenesulfonamide;(NZ)-4-methyl-N-[methyl(phenyl)-lambda4-sulfanylidene]benzenesulfonamide;NSC72486;MLS000539679;SCHEMBL17996453;XMOIPBDNUQHKJO-UHFFFAOYSA-N;NSC-72486;SMR000162009;AG-803/12478076;(NE)-4-methyl-N-[methyl(phenyl)-lambda4-sulfanylidene]benzenesulfonamide

Suppliers and Price of 4-methyl-N-[methyl(phenyl)-lambda~4~-sulfanylidene]benzenesulfonamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 4-methyl-N-[methyl(phenyl)-lambda~4~-sulfanylidene]benzenesulfonamide

Chemical Property:

Vapor Pressure:1.24E-08mmHg at 25°C
Boiling Point:472.2°Cat760mmHg
Flash Point:239.4°C
Density:1.24g/cm³
XLogP3:4.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:293.05442107
Heavy Atom Count:19
Complexity:411

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)N=S(C)C2=CC=CC=C2
Isomeric SMILES:CC1=CC=C(C=C1)S(=O)(=O)/N=S(/C)\C2=CC=CC=C2

Technology Process of 4-methyl-N-[methyl(phenyl)-lambda~4~-sulfanylidene]benzenesulfonamide

There total 4 articles about 4-methyl-N-[methyl(phenyl)-lambda~4~-sulfanylidene]benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 100-68-5
methyl-phenyl-thioether

: 55962-05-5
[N-(p-tolylsulfonyl)imino]phenyliodinane

: 10330-22-0,38227-94-0,205581-06-2,543681-35-2,543681-36-3
S-methyl-S-phenyl-N-(p-tolylsulfonyl)sulfilimine

Guidance literature:: copper acetylacetonate; In acetonitrile; at 25 ℃; for 1h;
DOI:10.1002/adsc.200404291

Reference yield: 80.0%

: 100-68-5
methyl-phenyl-thioether

: 127-65-1
chloroamine-T

: 10330-22-0,38227-94-0,205581-06-2,543681-35-2,543681-36-3
S-methyl-S-phenyl-N-(p-tolylsulfonyl)sulfilimine

Guidance literature:: In acetonitrile; at 20 ℃;
DOI:10.1002/jhet.5570420420

Reference yield:

: 108-98-5
thiophenol

: 10330-22-0,205581-06-2,38227-94-0,543681-35-2,543681-36-3
(S)-S-methyl-S-phenyl-N-(p-tolylsulfonyl)sulfimide

: 10330-22-0,205581-06-2,38227-94-0,543681-35-2,543681-36-3
(R)-S-methyl-S-phenyl-N-(p-tolylsulfonyl)sulfimide

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydroxide / ethanol / 2 h / 20 °C

1.2: 12 h / 20 °C

2.1: (S,S)-2,6-bis(4-phenyl-2-oxazolinyl)pyridine; iron(III) tris(4-chloro-2,6-dimethyl-3,5-heptanedionate) / acetone / 2 h / 0 °C

With iron(III) tris(4-chloro-2,6-dimethyl-3,5-heptanedionate); sodium hydroxide; (S,S)-2,6-bis(4-phenyl-2-oxazolinyl)pyridine; In ethanol; acetone;
DOI:10.1002/anie.201304451