Technology Process of Phosphorochloridamidic acid, N-(phenylmethyl)-N-2-propen-1-yl-,
phenyl ester
There total 1 articles about Phosphorochloridamidic acid, N-(phenylmethyl)-N-2-propen-1-yl-,
phenyl ester which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
O-phenyl phosphorodichloridate;
With
dmap; triethylamine;
In
dichloromethane;
at 20 ℃;
for 0.25h;
Allylbenzylamine;
In
dichloromethane;
at 20 ℃;
for 3h;
DOI:10.1016/j.jorganchem.2006.09.035
- Guidance literature:
-
acetophenone;
With
N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane;
In
tetrahydrofuran; toluene;
at -78 ℃;
for 0.166667h;
C16H17ClNO2P;
In
tetrahydrofuran; toluene;
at -78 - 20 ℃;
DOI:10.1016/j.jorganchem.2006.09.035
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: KHMDS; HMPA / tetrahydrofuran; toluene / 0.17 h / -78 °C
1.2: 95 percent / tetrahydrofuran; toluene / -78 - 20 °C
2.1: 35 percent / Grubbs second generation catalyst / CH2Cl2 / 24 h / Heating
With
N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane;
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride;
In
tetrahydrofuran; dichloromethane; toluene;
DOI:10.1016/j.jorganchem.2006.09.035
