trimethyl-[(4-methylphenyl)methyl]azanium

Base Information

• Chemical Name: trimethyl-[(4-methylphenyl)methyl]azanium
• CAS No.: 6140-16-5
• Molecular Formula: C11H18N+
• Molecular Weight: 291.175
• Mol file: 6140-16-5.mol

Synonyms:

Chemical Property of trimethyl-[(4-methylphenyl)methyl]azanium

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trimethyl-[(4-methylphenyl)methyl]azanium

There total 1 articles about trimethyl-[(4-methylphenyl)methyl]azanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

4-methyl-N,N-dimethylbenzylamine (4052-88-4) + methyl iodide (74-88-4) → N,N,N-trimethyl-1-(p-tolyl)methanaminium iodide (6140-16-5)

Guidance literature:

In ethyl acetate; at 20 ℃; for 1h;

DOI:10.1021/acs.joc.0c01274

Reference yield: 95.0%

4-methoxyphenylboronic acid (5720-07-0) + N,N,N-trimethyl-1-(p-tolyl)methanaminium iodide (6140-16-5) → 1-(4-methoxybenzyl)-4-methylbenzene (22865-60-7)

Guidance literature:

With potassium phosphate; (NC₅H₃(N₂C₇H₄(CH₂)3CH₃)2)NiBr⁽¹⁺⁾*Br^(1-)=Ni(NC₅H₃(N₂C₇H₄(CH₂)3CH₃)2)Br₂; triphenylphosphine; In 1,4-dioxane; at 80 ℃; for 24h; Schlenk technique;

DOI:10.1016/j.cclet.2016.09.006

Reference yield: 73.0%

N,N,N-trimethyl-1-(p-tolyl)methanaminium iodide (6140-16-5) + p-tert-butylphenylboronic acid (123324-71-0) → C18H22O2S

Guidance literature:

With potassium pyrosulfite; 3,4,7,8-Tetramethyl-o-phenanthrolin; cobalt(II) chloride; In N,N-dimethyl-formamide; at 120 ℃; for 24h; Schlenk technique; Inert atmosphere;

DOI:10.1002/cctc.202101716

upstream raw materials:

4-methyl-N,N-dimethylbenzylamine

methyl iodide

Downstream raw materials:

1-(4-methoxybenzyl)-4-methylbenzene

1,2-di-p-tolylethane

1-methyl-4-((phenylsulfonyl)methyl)benzene