Stannane, butyltricyclohexyl-

Base Information

• Chemical Name: Stannane, butyltricyclohexyl-
• CAS No.: 7067-44-9
• Molecular Formula: C22H42 Sn
• Molecular Weight: 425.285
• European Community (EC) Number: 230-358-5
• UNII: Z8QJQ95Q7H
• DSSTox Substance ID: DTXSID9064558
• Mol file: 7067-44-9.mol

Synonyms:Tricyclohexylbutyltin;Butyltricyclohexylstannane;Stannane, butyltricyclohexyl-;7067-44-9;Z8QJQ95Q7H;EINECS 230-358-5;butyl(tricyclohexyl)stannane;butyl tricyclohexyltin;UNII-Z8QJQ95Q7H;C22H42Sn;C22-H42-Sn;DTXSID9064558

Chemical Property of Stannane, butyltricyclohexyl-

Chemical Property:

• Boiling Point: 365-370 °C
• PSA: 0.00000
• Density: 1.56g/cm³
• LogP: 7.16880
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 426.230854
• Heavy Atom Count: 23
• Complexity: 273

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](C1CCCCC1)(C2CCCCC2)C3CCCCC3

Technology Process of Stannane, butyltricyclohexyl-

There total 3 articles about Stannane, butyltricyclohexyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

tricyclohexyltin hydride (6056-50-4) + 1-Bromoheptane (629-04-9) → (cyclo-C6H11)3SnC4H9 (7067-44-9) + n-heptane (142-82-5)

Guidance literature:

With n-butyllithium; In hexane; 1-bromoheptane (1 equiv.) and TMTH (1 equiv.) in hexane cooled to 0°C under Ar, n-BuLi (1 equiv., 2.40 M in hexane) added, stirred for 15 min, quenched with water; analyzed by GC;

DOI:10.1021/om00146a021

Reference yield:

1-bromocyclohexane (108-85-0) + cyclohexyl chloride (542-18-7) + Trichlorbutylstannan (1118-46-3) → (cyclo-C6H11)3SnC4H9 (7067-44-9)

Guidance literature:

With hydrogenchloride; magnesium; In tetrahydrofuran; cyclohexane; nitrogen; water;

Reference yield:

n-butyl magnesium bromide (693-03-8) + tris(cyclohexyl)tin bromide (3023-92-5) → (cyclo-C6H11)3SnC4H9 (7067-44-9)

Guidance literature:

In diethyl ether; refluxing;;

upstream raw materials:

1-bromocyclohexane

cyclohexyl chloride

Trichlorbutylstannan

n-butyl magnesium bromide

Downstream raw materials:

di(n-butyl)tin oxide

dibutyltin chloride

tricyclohexyltin(IV) chloride

Refernces

• 1、 -. "Process for preparing organotin compounds". . . Retrieved 2008/06/13.