palladium pivalate

Base Information

• Chemical Name: palladium pivalate
• CAS No.: 86430-54-8
• Molecular Formula: C₃₀H₅₄O₁₂Pd₃
• Molecular Weight: 926.012
• Mol file: 86430-54-8.mol

Synonyms:

Chemical Property of palladium pivalate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of palladium pivalate

There total 1 articles about palladium pivalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

methanol (67-56-1) + 1-phenyl-1H-indole (16096-33-6) + palladium(II) acetate trimer (53189-26-7) + sodium t-butanolate (865-48-5) → palladium(II) pivalate (106396-89-8,86430-54-8) + [Pd4(pivalato)6(MeO)2] (1381868-26-3) + [Pd4(pivalato)2(OAc)2(MeO)2(N-methylindole)2] (1381868-27-4) + [Pd4(pivalato)4(MeO)2(N-phenylindole)2] (1381868-28-5)

Guidance literature:

In methanol; treatment of N-phenylindole wuth (Pd(OAc)2)3 in the presence of PivONa in MeOH at room temp.;

DOI:10.1021/om300284t

Reference yield: 86.0%

palladium pivalate (86430-54-8,106396-89-8) + acetic acid (64-19-7,77671-22-8) → palladium(II) acetate trimer (53189-26-7)

Guidance literature:

at 100 ℃; for 5h; Inert atmosphere;

DOI:10.1021/acs.orglett.5b02835

Reference yield: 20.0%

palladium(II) pivalate (106396-89-8,86430-54-8) + o-xylene (95-47-6) + water (7732-18-5) + potassium hydroxide + N-phenyl-1,2-benzenediamine (534-85-0) → [K*H2O](Pd3(OOCCMe3)4(μ-OH)[μ-N,N-η2-N,N'-(N)(NPh)(C6H4)]2) dihydrate * 0.5(o-xylene)

Guidance literature:

With air; In o-xylene; dissolving of Pd3(OOCCMe3)6 and N-phenyl-o-phenylenediamine in Ar atmosphere of o-xylene; addn. of KOH, stirring for 1 h at 100°C; cooling to room temp., filtration, holding under Ar-air (1:1) atmosphere for 3d; crystn., elem. anal.;

DOI:10.1016/S0022-328X(01)01181-0

upstream raw materials:

methanol

1-phenyl-1H-indole

palladium(II) acetate trimer

sodium t-butanolate

Downstream raw materials:

palladium(II) acetate trimer