6434-78-2

Basic information

• Product Name: TRANS-2-NONENE
• Synonyms: 1-Hexyl-2-methylethylene;2-NONENE;TRANS-2-NONENE;(2E)-2-Nonene;(E)- and (Z)-2-Nonene;(E)-2-C9H18;(E)-2-Nonene;2-Nonene, (E)-
• CAS NO: 6434-78-2
• Molecular Formula: C₉H₁₈
• Molecular Weight: 126.24
• EINECS: 229-216-5
• Mol File: 6434-78-2.mol
• Article Data: 26

Chemical Properties

• Melting Point: -89.14°C (estimate)
• Boiling Point: 144-145 °C(lit.)
• Flash Point: 90 °F
• Appearance: /
• Density: 0.734 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.42(lit.)
• CAS DataBase Reference: TRANS-2-NONENE(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS-2-NONENE(6434-78-2)
• EPA Substance Registry System: TRANS-2-NONENE(6434-78-2)

Safety Data

• Statements: 10
• Safety Statements: 16-29-33
• RIDADR: UN 3295 3/PG 3
• WGK Germany: 3
• HazardClass: 3.2
• PackingGroup: III
• Hazardous Substances Data: 6434-78-2(Hazardous Substances Data)

Usage

General Description

Trans-2-nonene is a chemical compound that belongs to the family of alkenes, which are hydrocarbons with one or more carbon-carbon double bonds. It is a colorless liquid with a gasoline-like odor and is commonly used as a solvent and as a starting material in the production of other chemicals. It is a versatile compound that is used in various industries, including the production of polymers, synthetic lubricants, and surfactants. Trans-2-nonene is also used as a flavor and fragrance ingredient in the food and beverage industry. Additionally, it is employed in the synthesis of pharmaceuticals and agricultural chemicals. Overall, trans-2-nonene is a significant chemical with a wide range of applications in various fields.

InChI:InChI=1S/C9H18/c1-3-5-7-9-8-6-4-2/h3,5H,4,6-9H2,1-2H3/b5-3+

Upstream product

• 19447-29-1 non-2-yne 
• 111-66-0 oct-1-ene 
• 1822-71-5 n-pentylsodium 
• 185019-15-2 nonan-3-ol 
• 7758-99-8 copper(II) sulfate 
• 13389-42-9 trans-2-Octene 
• 7642-04-8 cis-2-octene 
• 124-18-5 decane 
• 201230-82-2 carbon monoxide 
• 111-71-7 heptanal 
• 83587-40-0 P-ethyl-N,N-dimethyl-P-phenylphosphinothioic amide 
• 1530-32-1 ethyltriphenylphosphonium bromide 
• 17847-85-7 triethyl(ethylidene)phosphorane 
• 109-72-8 n-butyllithium 

Downstream Products

• 111-14-8 oenanthic acid 
• 64-19-7 acetic acid 
• 111-84-2 nonane 
• 925-78-0 3-nonanone 
• 821-55-6 2-Nonanone 

Relevant articles and documents

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Carbonylative, Catalytic Deoxygenation of 2,3-Disubstituted Epoxides with Inversion of Stereochemistry: An Alternative Alkene Isomerization Method

Reactions facilitating inversion of alkene stereochemistry are rare, sought-after transformations in the field of modern organic synthesis. Although a number of isomerization reactions exist, most methods require specific, highly activated substrates to achieve appreciable conversion without side product formation. Motivated by stereoinvertive epoxide carbonylation reactions, we developed a two-step epoxidation/deoxygenation process that results in overall inversion of alkene stereochemistry. Unlike most deoxygenation systems, carbon monoxide was used as the terminal reductant, preventing difficult postreaction separations, given the gaseous nature of the resulting carbon dioxide byproduct. Various alkyl-substituted cis- A nd trans-epoxides can be reduced to trans- A nd cis-alkenes, respectively, in >99:1 stereospecificity and up to 95% yield, providing an alternative to traditional, direct isomerization approaches.

METHOD FOR PRODUCING ORGANIC COMPOUND

PROBLEM TO BE SOLVED: To provide a method of subjecting a compound having on one carbon atom a carbon atom constituting a carbon-carbon double bond and a functional group such as a hydroxyl group to a reductive reaction condition and producing an organic compound having the functional group substituted with a hydrogen atom. SOLUTION: There is provided a method for producing a compound represented by a formula (50) from a raw material compound represented by a formula (10). The method includes a step of irradiating a reaction system with light, the reaction system comprising the raw material compound, a hydrogen source compound, and a catalyst having a palladium component supported by a carrier containing titanium oxide. (R11 to R15 are a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms which may have a cyclic structure or a derivative group thereof, or a heteroatom-containing group having 1 to 20 carbon atoms which may have a cyclic structure or a derivative group thereof; and R16 is a hydrogen atom, a hydrocarbon group having 1 to 40 carbon atoms or an acyl group having 1 to 20 carbon atoms which may have a cyclic structure, or -CH(CH2OH)2).) COPYRIGHT: (C)2015,JPO&INPIT