trans-2-Nonene

Base Information

• Chemical Name: trans-2-Nonene
• CAS No.: 2216-38-8
• Molecular Formula: C9H18
• Molecular Weight: 126.242
• Hs Code.: 2901299090
• European Community (EC) Number: 229-216-5,678-276-2
• UNII: W20AXW806F
• DSSTox Substance ID: DTXSID60883134
• Nikkaji Number: J87.937A,J87.938J
• Wikidata: Q27292204
• Mol file: 2216-38-8.mol

Synonyms:trans-2-Nonene;6434-78-2;2-Nonene;(E)-Non-2-ene;2-Nonene, (E)-;(E)-2-Nonene;2-Nonene, (2E)-;(2E)-2-Nonene;UNII-W20AXW806F;(2E)-NON-2-ENE;HSDB 756;W20AXW806F;EINECS 229-216-5;EINECS 248-339-5;2216-38-8;Noneno;n-Nonenes;n-Nonene;MFCD00009549;UNII-M0TB9RXK4B;Nonene (all isomers);EC 248-339-5;.BETA.-TRANS-NONENE;DTXSID60883134;CAA21638;(E)-2-C9H18;LS-166168;D91716;ethyl[2-(boc-amino)ethylamino]acetatehydrochloride;Q27292204

Chemical Property of trans-2-Nonene

Chemical Property:

• Melting Point: -89.14°C (estimate)
• Refractive Index: n20/D 1.42(lit.)
• Boiling Point: 150.5°Cat760mmHg
• Flash Point: 32.2°C
• PSA: 0.00000
• Density: 0.739g/cm³
• LogP: 3.53290
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 126.140850574
• Heavy Atom Count: 9
• Complexity: 62.4

Purity/Quality:

98% ^*data from raw suppliers

2-Nonene (cis- and trans- mixture) >94.0%(GC) ^*data from reagent suppliers

Safty Information:

• Statements: 10
• Safety Statements: 16-29-33

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Unsaturated
• Canonical SMILES: CCCCCCC=CC
• Isomeric SMILES: CCCCCC/C=C/C

Technology Process of trans-2-Nonene

There total 9 articles about trans-2-Nonene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

oct-1-ene (111-66-0,25068-25-1) → 3‐decene (19398-37-9) + 4-octene (592-99-4,7642-15-1,14850-23-8) + oct-3-ene (14850-22-7,14919-01-8,138663-42-0,592-98-3) + 2-octene (111-67-1) + (E,Z)-tridec-6-ene (24949-38-0) + dodecene-5 (42714-70-5) + 4-undecene (20810-21-3) + tetradec-7-ene (10374-74-0) + cis,trans-2-nonylene (2216-38-8)

Guidance literature:

With rhenium(VII) oxide on aluminum oxide; In supercritical CO₂; at 35 ℃; for 2h; under 67506.8 Torr; chemoselective reaction; Inert atmosphere; Autoclave;

DOI:10.1039/b815121k

Reference yield:

oct-1-ene (111-66-0,25068-25-1) → 1-Heptene (592-76-7) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + ethene (74-85-1) + (E,Z)-tridec-6-ene (24949-38-0) + tetradec-7-ene (10374-74-0) + cis,trans-2-nonylene (2216-38-8)

Guidance literature:

With benzylidene-chloro(1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)-[1-(2′-pyridinyl)-2,4-dimethylpentan-3-olato]ruthenium; at 60 ℃; for 7h; Reagent/catalyst; Temperature; Time; Catalytic behavior;

DOI:10.3390/molecules19055522

Reference yield:

1-decanoic acid (334-48-5) → caprinaldehyde (112-31-2) + 3‐decene (19398-37-9) + nonane (111-84-2) + decane (124-18-5) + non-1-ene (124-11-8) + 1-Decanol (112-30-1) + decylthiol (143-10-2) + 1-(methylthio)decane (22438-39-7) + 3-nonene (20063-77-8) + 1-Decene (872-05-9,17438-89-0,25189-70-2) + decyl decanoate (1654-86-0) + 2-decene (20063-97-2,20348-51-0,6816-17-7) + S-methyl decanethioate (1680-29-1) + decyl thiomethanoate + cis,trans-2-nonylene (2216-38-8)

Guidance literature:

With nickel-molybdenum sulfide; Dimethyldisulphide; C₈H₁₅N₂⁽¹⁺⁾*C₈H₁₈NO₄S₂^(1-); In n-heptane; toluene; at 339.84 ℃; under 30003 Torr; Ionic liquid;

DOI:10.1016/j.apcata.2016.12.020

upstream raw materials:

Nona-1,2-dien

oct-1-ene

5-nonanol

non-1-ene

Downstream raw materials:

caprinaldehyde

2-hexyl-3-methyl-oxirane

heptanal

2-methyl-1-nonanal

Refernces

• 1、 Chulsky, Karina,Dobrovetsky, Roman. "Metal-Free Catalytic Reductive Cleavage of Enol Ethers". supporting information. p. 6804 - 6807. Retrieved 2018/11/02.
• 2、 Karakhanov, Eduard,Maksimov, Anton,Kardasheva, Yulia,Runova, Elena,Zakharov, Roman,Terenina, Maria,Kenneally, Corey,Arredondo, Victor. "Methylformate as replacement of syngas in one-pot catalytic synthesis of amines from olefins". . p. 540 - 547. Retrieved 2014/02/14.