(E)-3,7-Dimethyl-2,7-octadienyl propionate

Base Information

Chemical Name:(E)-3,7-Dimethyl-2,7-octadienyl propionate
CAS No.:75705-48-5
Molecular Formula:C13H22O2
Molecular Weight:210.316
Hs Code.:
Nikkaji Number:J135.832D,J777C
Metabolomics Workbench ID:4267
Mol file:75705-48-5.mol

Synonyms:75705-48-5;(E)-3,7-Dimethyl-2,7-octadienyl propionate;WE(8:2(2E,7E)(3Me,7Me)/3:0);2,7-Octadien-1-ol, 3,7-dimethyl-, propanoate, (E)-;SCHEMBL11392852;SCHEMBL11406318;LMFA07010622;3,7-Dimethyl-2,7-octadiene-1-ol propanoate;(E)-3,7-Dimethyl-2,7-octadien-1-ol propanoate;(e)-3,7-dimethyl-2,7-octadien-1-yl propanoate

Suppliers and Price of (E)-3,7-Dimethyl-2,7-octadienyl propionate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 18 raw suppliers

Chemical Property of (E)-3,7-Dimethyl-2,7-octadienyl propionate

Chemical Property:

Vapor Pressure:0.0038mmHg at 25°C
Boiling Point:280.4°Cat760mmHg
Flash Point:96.3°C
PSA：26.30000
Density:0.895g/cm³
LogP:3.63230
XLogP3:4.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:8
Exact Mass:210.161979940
Heavy Atom Count:15
Complexity:239

Purity/Quality:: 99% ,98%,Electron Grade , ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC(=O)OCC=C(C)CCCC(=C)C
Isomeric SMILES:CCC(=O)OC/C=C(\C)/CCCC(=C)C

Technology Process of (E)-3,7-Dimethyl-2,7-octadienyl propionate

There total 3 articles about (E)-3,7-Dimethyl-2,7-octadienyl propionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 104857-56-9
Propionic acid (E)-3,7-dimethyl-7-(2,2,2-trifluoro-acetoxy)-oct-2-enyl ester

: 105-90-8,27751-90-2
geranyl propionate

: 75705-48-5
3,7-dimethyl-2(E),7-octadienyl-1-propionate

Guidance literature:: at 220 ℃; Yield given. Yields of byproduct given;

Reference yield:

: 29021-98-5
3-(2-methyl-[1,3]dioxolan-2-yl)-propan-1-ol

: 75705-48-5
3,7-dimethyl-2(E),7-octadienyl-1-propionate

Guidance literature:: Multi-step reaction with 9 steps

1: 86 percent / pyridinium chlorochromate, sodium acetate / CH₂Cl₂ / 0.75 h / 25 °C

2: 1.) sodium hydride / 1.) ether, 25 deg C, 45 min, 2.) 3 h

3: 98 percent / hydrogen / 5percent Pd-C / methanol / 12 h / 25 °C

4: 93 percent / lithium aluminum hydride / diethyl ether / 2 h / 0 °C

5: 86 percent / hydrochloric acid / diethyl ether / 3 h / 25 °C

6: 97 percent / pyridine

7: 1.) sodium iodide, 2.) DBU / 1.) DMF, 50 deg C, 3.5 h, 2.) 80 deg C, 3.5 h

8: 1.) sodium hydride, 3.) aluminum chloride, lithium aluminum hydride / 1.) ether, 25 deg C, 1 h, 2.) 10 h, 3.) 0 deg C, 1 h

9: triethylamine / 24 h / 25 °C

With pyridine; hydrogenchloride; lithium aluminium tetrahydride; aluminium trichloride; hydrogen; sodium acetate; sodium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; pyridinium chlorochromate; sodium iodide; palladium on activated charcoal; In methanol; diethyl ether; dichloromethane;

Reference yield:

: 7-methyl-3-methylene-7-octenal diethyl acetal

: 79-03-8
propionyl chloride

: 73214-62-7
(Z)-3,7-dimethyl-2,7-octadien-1-yl propanoate

: 73214-63-8
7-methyl-3-methylene-7-octenyl propionate

: 75705-48-5
3,7-dimethyl-2(E),7-octadienyl-1-propionate

Guidance literature:: 7-methyl-3-methylene-7-octenal diethyl acetal; With formic acid; acetic acid; In water; at 70 - 80 ℃; for 8h;

With sodium tetrahydroborate; sodium hydroxide; In ethanol; water; at 15 - 20 ℃; for 16h; Inert atmosphere; Cooling with ice;

propionyl chloride; With pyridine; In tetrahydrofuran; for 19h; Inert atmosphere; Cooling with ice;