Dibenzanilide

Base Information

• Chemical Name: Dibenzanilide
• CAS No.: 3027-01-8
• Molecular Formula: C20H15NO2
• Molecular Weight: 301.345
• Hs Code.: 2924299090
• European Community (EC) Number: 659-691-8
• NSC Number: 137617
• DSSTox Substance ID: DTXSID40952630
• Nikkaji Number: J807.318J
• Wikidata: Q82931293
• ChEMBL ID: CHEMBL2135348
• Mol file: 3027-01-8.mol

Synonyms:N-Phenyl-dibenzamid;N-benzoyl-N-phenyl-benzamide;N.N-Dibenzoyl-anilin;N-Phenyldibenzamide;Dibenzanilid;N,N-dibenzoylphenylamine;Benzamide, N-benzoyl-N-phenyl-;Dibenzanilide;

Chemical Property of Dibenzanilide

Chemical Property:

• Vapor Pressure: 7.07E-09mmHg at 25°C
• Boiling Point: 466.4°Cat760mmHg
• Flash Point: 206.2°C
• PSA: 37.38000
• Density: 1.223g/cm³
• LogP: 4.17380
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 301.110278721
• Heavy Atom Count: 23
• Complexity: 372

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=O)N(C2=CC=CC=C2)C(=O)C3=CC=CC=C3

Technology Process of Dibenzanilide

There total 24 articles about Dibenzanilide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

N-phenyl benzoyl amide (93-98-1,5705-51-1) + benzaldehyde (100-52-7) → N,N-dibenzoylaniline (3027-01-8)

Guidance literature:

With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; vitamin B₁; [Co(13-TMC)(ACN)](ClO₄)₂; C₁₉H₁₅N₂⁽¹⁺⁾*ClO₄^(1-); Fe(EDTA)*H₂O₂; potassium carbonate; potassium hydrogencarbonate; In water; at 20 ℃; for 12h; Reagent/catalyst; chemoselective reaction;

DOI:10.1002/cctc.202000156

Reference yield: 91.0%

N-phenyl-benzimidoyl chloride (4903-36-0) + benzoic acid (65-85-0,8013-63-6) → N,N-dibenzoylaniline (3027-01-8)

Guidance literature:

With sodium hydroxide; tetrabutylammomium bromide; In dichloromethane; water; for 3h; Ambient temperature;

DOI:10.1055/s-1980-28934

Reference yield: 85.0%

N-phenyl benzoyl amide (93-98-1,5705-51-1) + benzoyl chloride (98-88-4) → N,N-dibenzoylaniline (3027-01-8)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; for 4h; Heating;

DOI:10.1021/ma0401370

upstream raw materials:

pyridine

N-phenyl benzoyl amide

benzoyl chloride

diphenylmethanone O-benzoyl oxime

Downstream raw materials:

N-benzylbenzamide

2-methyl-1,3,3-triphenylprop-2-ene-1-one

Refernces

• 1、 Siddiqui, Asher M.,Khalid, Anam,Khan, Arif,Azad, Chandra S.,Samim, Mohd.,Khan, Imran A.. "N-Heterocyclic Carbene/Cobalt Cooperative Catalysis for the Chemo- and Regioselective C?N Bond Formation between Aldehyde and Amines/Amides". . p. 4281 - 4287. Retrieved 2020/07/24.
• 2、 Kondo, Kazuhiro,Murakami, Yasuoki. "2-chloro-N,N-dibenzoylaniline: A selective N-benzoylating reagent". . p. 1217 - 1219. Retrieved 2007/10/03.