Tris[4-(dimethylamino)phenyl]silyl

Base Information

• Chemical Name: Tris[4-(dimethylamino)phenyl]silyl
• CAS No.: 18733-97-6
• Molecular Formula: C24H30N3Si
• Molecular Weight: 389.616
• NSC Number: 405758
• DSSTox Substance ID: DTXSID00422667
• Wikidata: Q82234639
• Mol file: 18733-97-6.mol

Synonyms:18733-97-6;NSC405758;SCHEMBL11044281;DTXSID00422667;tris(4-dimethylaminophenyl)-silane;Tris[4-(dimethylamino)phenyl]silyl;NSC-405758

Chemical Property of Tris[4-(dimethylamino)phenyl]silyl

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 388.220899504
• Heavy Atom Count: 28
• Complexity: 376

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)C1=CC=C(C=C1)[Si](C2=CC=C(C=C2)N(C)C)C3=CC=C(C=C3)N(C)C

Technology Process of Tris[4-(dimethylamino)phenyl]silyl

There total 5 articles about Tris[4-(dimethylamino)phenyl]silyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-dimethylaminophenylmagnesium bromide (7353-91-5) → Tri(4-N,N-dimethylaminophenyl)silane (18733-97-6)

Guidance literature:

With trichlorosilane; In tetrahydrofuran; for 14h; Ambient temperature;

DOI:10.1002/chem.19970030409

Reference yield: 93.0%

(p-dimethylamino)phenylsilane (35490-64-3) → Tri(4-N,N-dimethylaminophenyl)silane (18733-97-6)

Guidance literature:

With C₃₀H₅₄CaN₄Si; In benzene-d6; at 50 ℃; for 2h; Inert atmosphere;

DOI:10.1021/acscatal.1c00463

Reference yield: 49.0%

trichlorosilane (10025-78-2) + 4-dimethylaminophenyllithium (13190-50-6) → Tri(4-N,N-dimethylaminophenyl)silane (18733-97-6)

Guidance literature:

In not given;

DOI:10.1021/ja01148a079

upstream raw materials:

(ph-4-Nme₂)3SiCl

4-dimethylaminophenyllithium

4-dimethylaminophenylmagnesium bromide

trichlorosilane

Downstream raw materials:

(ph-4-Nme₂)3SiOH

Refernces

• 1、 Knoelker, Hans-Joachim,Foitzik, Norbert,Goesmann, Helmut,Graf, Regina,Jones, Peter G.,Wanzl, Guenter. "Highly stereoselective synthesis of bicyclo[n.3.0]alkanes by titanium tetrachloride promoted [3 + 2] cycloaddition of allylsilanes and 1-acetylcycloalkenes". . p. 538 - 551. Retrieved 2007/10/03.