Trimethyl-(2-trimethylsilylphenoxy)silane

Base Information

• Chemical Name: Trimethyl-(2-trimethylsilylphenoxy)silane
• CAS No.: 18036-83-4
• Molecular Formula: C12H22OSi2
• Molecular Weight: 238.477
• NSC Number: 96867
• DSSTox Substance ID: DTXSID70294515
• Nikkaji Number: J2.822.193B
• Wikidata: Q82033868
• Mol file: 18036-83-4.mol

Synonyms:18036-83-4;trimethyl-(2-trimethylsilylphenoxy)silane;Trimethyl[2-(trimethylsiloxy)phenyl]silane;trimethyl-(2-trimethylsilyloxyphenyl)silane;NSC96867;DTXSID70294515;MFCD18074403;NSC-96867;AKOS025310325;trimethyl[2-(trimethylsilyl)phenoxy]silane

Chemical Property of Trimethyl-(2-trimethylsilylphenoxy)silane

Chemical Property:

• Vapor Pressure: 0.0463mmHg at 25°C
• Boiling Point: 244.9°C at 760 mmHg
• Flash Point: 84.3°C
• Density: 0.89g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 238.12091839
• Heavy Atom Count: 15
• Complexity: 203

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C1=CC=CC=C1O[Si](C)(C)C

Technology Process of Trimethyl-(2-trimethylsilylphenoxy)silane

There total 6 articles about Trimethyl-(2-trimethylsilylphenoxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

chloro-trimethyl-silane (75-77-4) + (2-chlorophenoxy)trimethylsilane (17881-65-1) → o-(trimethylsilyl)phenol trimethylsilyl ether (18036-83-4)

Guidance literature:

chloro-trimethyl-silane; With sodium; In toluene; Reflux; Inert atmosphere;

(2-chlorophenoxy)trimethylsilane; In toluene; Reflux; Inert atmosphere;

DOI:10.1055/s-0029-1218631

Reference yield: 78.0%

chloro-trimethyl-silane (75-77-4) + o-Lithio-lithiumphenolat → o-(trimethylsilyl)phenol trimethylsilyl ether (18036-83-4)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 24h;

Reference yield: 67.0%

chloro-trimethyl-silane (75-77-4) + phenol (108-95-2,27073-41-2) → o-(trimethylsilyl)phenol trimethylsilyl ether (18036-83-4)

Guidance literature:

With tert.-butyl lithium; In pentane; 1.) room t., 2 h; 2.) room t., 14 h;

DOI:10.1021/ja00294a073

upstream raw materials:

chloro-trimethyl-silane

(2-chlorophenoxy)trimethylsilane

phenol

2-hydroxybromobenzene

Downstream raw materials:

o-(trimethylsilyl)phenol

2-(trimethylsilyl)phenyl trifluoromethanesulfonate

2-(tert-butyl)-2,3-dihydro-3-phenyl-1,2-benzoisoxazole

2-(trimethylsilyl)phenyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate