(2-CHLOROPHENOXY)TRIMETHYLSILANE 97

Base Information

• Chemical Name: (2-CHLOROPHENOXY)TRIMETHYLSILANE 97
• CAS No.: 17881-65-1
• Molecular Formula: C9H13 Cl O Si
• Molecular Weight: 200.74
• Hs Code.: 2931900090
• Mol file: 17881-65-1.mol

Synonyms:Silane,(2-chlorophenoxy)trimethyl- (9CI); Silane, (o-chlorophenoxy)trimethyl- (8CI);2-Chloro(trimethylsiloxy)benzene; 2-Chlorophenyl trimethylsilyl ether;o-Chlorophenol trimethyl silyl ether

Chemical Property of (2-CHLOROPHENOXY)TRIMETHYLSILANE 97

Chemical Property:

• Vapor Pressure: 0.003mmHg at 25°C
• Refractive Index: n20/D 1.494(lit.)
• Boiling Point: 202 °C(lit.)
• Flash Point: 170 °F
• PSA: 9.23000
• Density: 1.038 g/mL at 25 °C(lit.)
• LogP: 6.81660

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Chlorophenoxytrimethylsilane ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (2-CHLOROPHENOXY)TRIMETHYLSILANE 97

There total 12 articles about (2-CHLOROPHENOXY)TRIMETHYLSILANE 97 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-monochlorophenol (95-57-8) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → (2-chlorophenoxy)trimethylsilane (17881-65-1)

Guidance literature:

With poly(N-bromobenzene-1,3-disulfonamide); for 0.05h; Irradiation;

DOI:10.1016/j.tetlet.2006.03.157

Reference yield: 98.0%

chloro-trimethyl-silane (75-77-4) + 2-monochlorophenol (95-57-8) → (2-chlorophenoxy)trimethylsilane (17881-65-1)

Guidance literature:

Schlenk technique; Inert atmosphere; Reflux;

DOI:10.1039/c6ob00885b

Reference yield: 95.0%

2-monochlorophenol (95-57-8) + allyl-trimethyl-silane (762-72-1) → propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + (2-chlorophenoxy)trimethylsilane (17881-65-1)

Guidance literature:

iodine; In chloroform; at 60 ℃; for 0.5h;

DOI:10.1246/cl.1981.85

upstream raw materials:

chloro-trimethyl-silane

2-monochlorophenol

N,O-Bis(trimethylsilyl)trifluoroacetamide

C₈H₁₀ClOP

Downstream raw materials:

o-(trimethylsilyl)phenol trimethylsilyl ether

[2-(ethyl-dimethyl-silanyloxy)-phenyl]-trimethyl-silane

ethoxy-dimethyl-(2-trimethylsilanyloxy-phenyl)-silane

2-chlorophenyl 3-phenylpropionate