Dihydroxychloranium

Base Information

• Chemical Name: Dihydroxychloranium
• CAS No.: 14998-27-7
• Molecular Formula: ClO2
• Molecular Weight: 67.4518
• Mol file: 14998-27-7.mol

Synonyms:dihydroxychloranium;CHEBI:184408

Chemical Property of Dihydroxychloranium

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 40.13000
• Density: g/cm³
• LogP: 0.45190
• XLogP3: -0.1
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 68.9743320
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

CHLORITE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: O[Cl+]O

Technology Process of Dihydroxychloranium

There total 50 articles about Dihydroxychloranium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium azide + chlorine dioxide (10049-04-4,25052-55-5) → nitrogen (7727-37-9) + chlorite (14998-27-7) + chloride (16887-00-6) + Nitrate (14797-55-8) + dinitrogen monoxide (10024-97-2)

Guidance literature:

In water; react. of ClO2 in H2O with excess azide at 25.degreee.C at pH ca 7, maintaining of ionic strength at 0.10 M by addn. of NaClO4; not isolated; monitored by spectrophotometry at 360 nm;; Kinetics;

DOI:10.1021/ja00062a030

Reference yield:

sodium perchlorate → chlorine dioxide (10049-04-4,25052-55-5) + chlorite (14998-27-7) + chloride (16887-00-6) + chlorate (14866-68-3,80434-34-0)

Guidance literature:

In water; other Radiation; γ-radiation of 1 - 8 M NaClO4 soln. at -38 - -196°C;;

Reference yield:

sodium perchlorate → chlorine dioxide (10049-04-4,25052-55-5) + chlorite (14998-27-7) + chloride (16887-00-6) + dihydrogen peroxide (7722-84-1) + chlorate (14866-68-3,80434-34-0)

Guidance literature:

In water; other Radiation; γ-radiation of concd. NaClO4 soln.; influence of NaClO4 concn.;; Kinetics;

DOI:10.1021/j100863a033

upstream raw materials:

chlorine dioxide

4-fluorophenolate anion

p-bromophenoxide ion

4-iodophenoxide

Downstream raw materials:

chlorine dioxide

phenolate

p-bromophenoxide ion

cyanate

Refernces

• 1、 Lednicky,Stanbury. "OXIDATION OF TRIS(1,10-PHENANTHROLINE)IRON(II) BY CHLORINE DIOXIDE.". . p. 3098 - 3101. Retrieved 1983.
• 2、 Umile, Thomas P.,Wang, Dong,Groves, John T.. "Dissection of the mechanism of manganese porphyrin-catalyzed chlorine dioxide generation". . p. 10353 - 10362. Retrieved 2011/11/29.
• 3、 Wang, Lu,Margerum, Dale W.. "Hypohalite ion catalysis of the disproportionation of chlorine dioxide". . p. 6099 - 6105. Retrieved 2008/10/08.