Thallium chloride (TlCl2)

Base Information

• Chemical Name: Thallium chloride (TlCl2)
• CAS No.: 7791-12-0
• Molecular Formula: ClTl
• Molecular Weight: 239.836
• Hs Code.: 28273985
• UNII: 37CB58V15B
• DSSTox Substance ID: DTXSID6024333
• Nikkaji Number: J44.223B
• Mol file: 7791-12-0.mol

Synonyms:Thallium chloride (TlCl2);15230-71-4;Cl2Tl;Thalium(I) chloride;Cl2-Tl;THALLIUM CHLORIDE [MI];DTXSID6024333;THALLOUS CHLORIDE [HSDB]

Chemical Property of Thallium chloride (TlCl2)

Chemical Property:

• Appearance/Colour: white, odorless crystalline
• Vapor Pressure: 10 mm Hg ( 517 °C)
• Melting Point: 430 °C(lit.)
• Refractive Index: 2.247
• Boiling Point: 720 °C
• PSA: 0.00000
• Density: 7 g/mL at 25 °C(lit.)
• LogP: 0.68950
• Storage Temp.: Poison room
• Sensitive.: Air Sensitive
• Solubility.: ethanol: insoluble(lit.)
• Water Solubility.: Slightly soluble in water. Insoluble in alcohol, and acetone.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 239.94328
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

98%min ^*data from raw suppliers

Thallium(I) chloride 99.999% trace metals basis ^*data from reagent suppliers

Safty Information:

• Pictogram(s): As for thallium.
• Hazard Codes: T+,N
• Statements: 26/28-33-51/53
• Safety Statements: 13-28-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Tl+]
• Uses: Catalyst (chlorination), suntan lamp monitors. It is used as a catalyst in chlorination's and in suntan lamps. The low solubility of TlCl is exploited in chemical synthesis: treatment of metal chloride complexes with TlPF6, gives the corresponding metal hexafluorophosphate derivative. It is used as a tracer in medical imaging. Used to prepare cage, dinuclear complexes (TI-cyclodiphosphazanes) which possess interesting metal-metal interactions.

Technology Process of Thallium chloride (TlCl2)

There total 225 articles about Thallium chloride (TlCl2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

(NEt4)2[Fe5MoC(CO)17] + thallium(I) tetrafluoroborate (28625-02-7) + (triphenylphosphine)silver iodide (61026-08-2) → thallium chloride (55172-29-7,7791-12-0) + (NEt4)[Fe5MoAgC(CO)17(PPh3)] + N,N,N,N-tetraethylammonium tetrafluoroborate (429-06-1)

Guidance literature:

In tetrahydrofuran; under N2 atm. IAgPPh3 and TlBF4 were added to soln. (NEt4)2(Fe5MoC(CO)17) in THF at -5°C and stirred for 1 h; Et2O was added and mixt. was cooled for 2 h to -30°C, ppt. was filtered, filtrate was evapd. to dryness, residue was extd. with CH2Cl2, hexane was added, soln. was cooled to -30°C overnight; elem. anal.;

DOI:10.1021/om000976k

Reference yield: 57.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + (NEt4)2[Fe5MoC(CO)17] + thallium(I) tetrafluoroborate (28625-02-7) → thallium chloride (55172-29-7,7791-12-0) + (NEt4)[Fe5MoAuC(CO)17(PPh3)] + N,N,N,N-tetraethylammonium tetrafluoroborate (429-06-1)

Guidance literature:

In tetrahydrofuran; under N2 atm. ClAuPPh3 and TlBF4 were added to soln. (NEt4)2(Fe5MoC(CO)17) in THF at -5°C and stirred for 1 h; Et2O was added and mixt. was cooled for 2 h to -30°C, ppt. was filtered, filtrate was evapd. to dryness, residue was extd. with CH2Cl2, hexane was added, soln. was cooled to -30°C overnight; elem. anal.;

DOI:10.1021/om000976k

Reference yield: 55.0%

(NEt4)2[Fe5MoC(CO)17] + thallium(I) tetrafluoroborate (28625-02-7) + tetrameric (triphenylphosphine)copper(I) iodide (47107-74-4) → thallium chloride (55172-29-7,7791-12-0) + (NEt4)[Fe5MoCuC(CO)17(PPh3)] + N,N,N,N-tetraethylammonium tetrafluoroborate (429-06-1)

Guidance literature:

In tetrahydrofuran; under N2 atm. ICuPPh3 and TlBF4 were added to soln. (NEt4)2(Fe5MoC(CO)17) in THF at -5°C and stirred for 1 h; Et2O was added and mixt. was cooled for 2 h to -30°C, ppt. was filtered, filtrate was evapd. to dryness, residue was extd. with CH2Cl2, hexane was added, soln. was cooled to -30°C overnight; elem. anal.;

DOI:10.1021/om000976k

upstream raw materials:

sodium chloride

trichlorophosphate

hydrogenchloride

thallium(I) perchlorate

Downstream raw materials:

thallium(I) bis(isopropylamido)phenylborane

thallium(I) bis(tert-butylamido)phenylborane

sulfur

thallium(I) sulfide

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