dimethyl (Z)-hex-2-enedioate

Base Information

Chemical Name:dimethyl (Z)-hex-2-enedioate
CAS No.:6108-58-3
Molecular Formula:C8H12 O4
Molecular Weight:172.181
Hs Code.:2917190090
NSC Number:69192
Nikkaji Number:J1.938.356C
Mol file:6108-58-3.mol

Synonyms:dimethyl (Z)-hex-2-enedioate;2-Hexenedioic acid, dimethyl ester, (Z)-;6108-58-3;NSC69192;Dimethyl (2Z)-2-hexenedioate #;QPFMISCWBTXLFC-HYXAFXHYSA-N;NSC-69192;(Z)-2-Hexenedioic acid dimethyl ester

Suppliers and Price of dimethyl (Z)-hex-2-enedioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
HEX-2-ENEDIOIC ACID DIMETHYL ESTER 95.00%
5MG
$ 501.77

Total 5 raw suppliers

Chemical Property of dimethyl (Z)-hex-2-enedioate

Chemical Property:

Vapor Pressure:3E-06mmHg at 25°C
Boiling Point:388.7°C at 760 mmHg
Flash Point:188.9°C
PSA：52.60000
Density:1.343g/cm³
LogP:0.66880
XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:172.07355886
Heavy Atom Count:12
Complexity:184

Purity/Quality:: HEX-2-ENEDIOIC ACID DIMETHYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)CCC=CC(=O)OC
Isomeric SMILES:COC(=O)CC/C=C\C(=O)OC

Technology Process of dimethyl (Z)-hex-2-enedioate

There total 5 articles about dimethyl (Z)-hex-2-enedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: 6108-58-3
Δ²-dimethyl dihydromuconate

: 5621-44-3
dimethyl 2-methylenepentanedioate

Guidance literature:: With 1-methyl-pyrrolidin-2-one; methanol; ruthenium trichloride; triphenyl-arsane; hydroquinone; at 145 ℃; for 48h; Reagent/catalyst; Time;
DOI:10.1080/00958972.2014.956662

Reference yield:

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: 6108-58-3
Δ²-dimethyl dihydromuconate

: 41820-27-3
Δ³-dimethyl dihydromuconate

: 5621-44-3
dimethyl 2-methylenepentanedioate

Guidance literature:: With tetrafluoroboric acid diethyletherate; tris[tert-butyl]phosphonium tetrafluoroborate; 1-hydrogeno-3-butylimidazolium tetrafluoroborate; palladium(II) acetylacetonate; at 80 ℃; for 1h; Further Variations:; Catalysts; Reagents; Product distribution;
DOI:10.1002/adsc.200303025

Reference yield:

: 25126-93-6
dimethyl trans-3-hexene-1,6-dioate

: 201230-82-2
carbon monoxide

: 627-93-0
hexanedioic acid dimethyl ester

: 6108-58-3
Δ²-dimethyl dihydromuconate

: dimethyl 3-formylhexanedioate

Guidance literature:: With (acetylacetonato)dicarbonylrhodium (l); hydrogen; tris-(o-tolyl)phosphine; In tetrahydrofuran; at 70 ℃; for 16h; under 3750.38 - 15001.5 Torr; Reagent/catalyst; Schlenk technique; Autoclave;
DOI:10.1021/acs.joc.6b02939