Chromium,pentacarbonyl[(dimethylamino)phenylmethylene]-)(OC-6-21)-

Base Information

Chemical Name:Chromium,pentacarbonyl[(dimethylamino)phenylmethylene]-)(OC-6-21)-
CAS No.:30971-68-7
Molecular Formula:C14H11 Cr N O5
Molecular Weight:325.241
Hs Code.:

Synonyms:Chromium,pentacarbonyl[(dimethylamino)phenylmethylene]-)(OC-6-21)-;Chromium, pentacarbonyl((dimethylamino)phenylmethylene)-), (OC-6-21)-;30971-68-7

Suppliers and Price of Chromium,pentacarbonyl[(dimethylamino)phenylmethylene]-)(OC-6-21)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Chromium,pentacarbonyl[(dimethylamino)phenylmethylene]-)(OC-6-21)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:2
Exact Mass:325.004227
Heavy Atom Count:21
Complexity:314

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CN(C)C(=[Cr])C1=CC=CC=C1.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

Technology Process of Chromium,pentacarbonyl[(dimethylamino)phenylmethylene]-)(OC-6-21)-

There total 5 articles about Chromium,pentacarbonyl[(dimethylamino)phenylmethylene]-)(OC-6-21)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 26160-57-6
pentacarbonyl(ethoxyphenylmethylene)chromium⁽⁰⁾

: 30971-68-7
pentacarbonyl[(N,N-dimethylamino)phenylmethylene]chromium⁽⁰⁾

Guidance literature:: DOI:10.1021/ja00047a018

Reference yield: 93.0%

: disodium pentacarbonylchromium

: 611-74-5
N,N-dimethylbenzamide

: 30971-68-7
pentacarbonyl[(N,N-dimethylamino)phenylmethylene]chromium⁽⁰⁾

Guidance literature:: With aluminum oxide; chloro-trimethyl-silane; In tetrahydrofuran; N,N-dimethylbenzamide is added to Na2Cr(CO)5 in THF under Ar at -78°C, stirring for 0.5 h, then stirring at 0°C for 0.5 h, mixt. is treated with trimethylsilyl chloride and stirred at -78°C for 0.5 h, neutral Al2O3 is added; warming to room temp., evapn., dried under high vac., chromd. on SiO2 (hexane, CH2Cl2/hexane);
DOI:10.1021/om00093a021

Reference yield: 92.0%

: (pentacarbonylchromium)(C(C₆H₅)SC₆H₁₁)

: 124-40-3
dimethyl amine

: 1569-69-3
Cyclohexanethiol

: 30971-68-7
pentacarbonyl[(N,N-dimethylamino)phenylmethylene]chromium⁽⁰⁾

Guidance literature:: With sodium hydroxide; In diethyl ether; under inert gas; soln. of Cr-complex ether, addn. of 40% aq. Me2NH soln., addn. of NaOH, color change from deep brown to yellow; ether phase dried (Na2SO4), evapn. (20°C/15 Torr); elem. anal.;