methylcarbamic acid - methanamine (1:1)

Base Information

• Chemical Name: methylcarbamic acid - methanamine (1:1)
• CAS No.: 65398-48-3
• Molecular Formula: C3H10N2O2
• Molecular Weight: 106.125
• Mol file: 65398-48-3.mol

Synonyms:

Chemical Property of methylcarbamic acid - methanamine (1:1)

Chemical Property:

• Vapor Pressure: 0.0959mmHg at 25°C
• Boiling Point: 206.5°C at 760 mmHg
• Flash Point: 78.7°C

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methylcarbamic acid - methanamine (1:1)

There total 2 articles about methylcarbamic acid - methanamine (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.2%

carbon dioxide (124-38-9,18923-20-1) + methylamine (74-89-5) → methylammonium N-methylcarbamate (65398-48-3)

Guidance literature:

In ethanol; at 80 ℃; for 10h; under 90 - 110 Torr; Autoclave;

DOI:10.1039/d0ra07814j

Reference yield:

methylammonium carbonate (15719-64-9,15719-76-3,97762-63-5) + methylamine (74-89-5) → methylammonium N-methylcarbamate (65398-48-3)

Guidance literature:

With diethyl ether; at 10 - 15 ℃;

Reference yield: 99.0%

methylammonium N-methylcarbamate (65398-48-3) + benzaldehyde (100-52-7) → N-Benzylidenemethylamine (622-29-7)

Guidance literature:

In neat (no solvent); at 25 ℃; for 3h; Inert atmosphere; Green chemistry;

DOI:10.1039/d0ra07814j

upstream raw materials:

methylammonium carbonate

methylamine

carbon dioxide

Downstream raw materials:

N,N'-Dimethylurea

trimethylsilyl N-methylcarbamate

carbon dioxide

methylamine

Refernces

• 1、 Davidson, Robert W. M.,Fuchter, Matthew J.. "Direct NHC-catalysed redox amidation using CO2 for traceless masking of amine nucleophiles". supporting information. p. 11638 - 11641. Retrieved 2016/10/04.
• 2、 Knausz, Dezsoe,Meszticzky, Aranka,Szakacs, Laszlo,Csakvari, Bela,Ujszaszy, Kalman. "TRIMETHYLSILYLATED N-ALKYL-SUBSTITUTED CARBAMATES. I. PREPARATION AND SOME REACTIONS". . p. 11 - 22. Retrieved 2007/10/02.