trans-3-Decene

Base Information

• Chemical Name: trans-3-Decene
• CAS No.: 19150-21-1
• Molecular Formula: C10H20
• Molecular Weight: 140.269
• Nikkaji Number: J97.369F,J82.859I
• Mol file: 19150-21-1.mol

Synonyms:trans-3-Decene;19150-21-1;(E)-dec-3-ene;3-Decene;3-Decene, (3E)-;(E)-3-Decene;(3E)-dec-3-ene;3-Decene, (E)-;TRANS-3-DECENE 95%;GVRWIAHBVAYKIZ-FNORWQNLSA-N;AKOS006271772;(E)-3-C10H20;19398-37-9

Chemical Property of trans-3-Decene

Chemical Property:

• Vapor Pressure: 2.08mmHg at 25°C
• Melting Point: -56.93°C (estimate)
• Refractive Index: 1.4195 (estimate)
• Boiling Point: 169°Cat760mmHg
• Flash Point: 45.5°C
• PSA: 0.00000
• Density: 0.749g/cm³
• LogP: 3.92300
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 140.156500638
• Heavy Atom Count: 10
• Complexity: 72.1

Purity/Quality:

98%Min ^*data from raw suppliers

trans-3-Decene 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCC=CCC
• Isomeric SMILES: CCCCCC/C=C/CC

Technology Process of trans-3-Decene

There total 35 articles about trans-3-Decene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1-Decene (872-05-9,17438-89-0,25189-70-2) → 5-decene (19689-19-1) + 4-decene (19689-18-0) + trans-3-decene (19150-21-1) + Decan-2-one (693-54-9) + 2-decene (20063-97-2,20348-51-0,6816-17-7)

Guidance literature:

With oxygen; 2,6-di-O-methyl-β-cyclodextrin; palladium(II) sulfate; H₉PV₆Mo₆O₄₀; copper(II) sulfate; In water; at 80 ℃; for 6h; under 750.06 Torr; Mechanism; Product distribution; influence of composition of catalytic mixture on selectivity of reaction;

Reference yield: 96.0%

3-decyne (2384-85-2) → trans-3-decene (19150-21-1) + cis-3-decene (19398-86-8)

Guidance literature:

With formic acid; dihydridotetrakis(triphenylphosphine)ruthenium; In N,N-dimethyl-formamide; at 20 ℃; for 36h; optical yield given as %de; stereoselective reaction; Inert atmosphere;

DOI:10.1002/chem.201001143

Reference yield: 89.6%

erythro-4-(trimethylsilyl)-3-decanol (74844-85-2) → trans-3-decene (19150-21-1)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; for 1h; Ambient temperature;

DOI:10.1021/jo01310a035

upstream raw materials:

but-1-enyl-propyl ether

n-hexylmagnesium bromide

1,2-dibromo-1-ethoxybutane

(E)-1-butenyl butyl ether

Downstream raw materials:

3,4-epoxydecane

acetaldehyde

butyraldehyde

crotonaldehyde

Refernces

• 1、 Fabre, J.-L.,Julia, M.. "Organic Synthesis with Sulfones n0XXIX Stereospecific hydrogenolysis of vinylic sulfones with grignards and transition metal catalysts (1).". . p. 4311 - 4314. Retrieved 1983.
• 2、 Thiam, Zeynabou,Abou-Hamad, Edy,Dereli, Busra,Liu, Lingmei,Emwas, Abdul-Hamid,Ahmad, Rafia,Jiang, Hao,Isah, Abdulrahman Adamu,Ndiaye, Papa Birame,Taoufik, Mostafa,Han, Yu,Cavallo, Luigi,Basset, Jean-Marie,Eddaoudi, Mohamed. "Extension of surface organometallic chemistry to metal?organic frameworks: Development of a well-defined single site [(≡Zr? O?)W(=O)(CH2TBu)3] olefin metathesis catalyst". supporting information. p. 16690 - 16703. Retrieved 2020/11/09.
• 3、 Larsen, Casey R.,Erdogan, Gulin,Grotjahn, Douglas B.. "General catalyst control of the monoisomerization of 1-alkenes to trans -2-alkenes". supporting information. p. 1226 - 1229. Retrieved 2014/02/14.