TRIS(PHENYL,METHYLPHENYL,ETHYLPHENYLANDNONYLPHENYL)PHOSPHATE

Base Information

• Chemical Name: TRIS(PHENYL,METHYLPHENYL,ETHYLPHENYLANDNONYLPHENYL)PHOSPHATE
• CAS No.: 10113-28-7
• Molecular Formula: C8H11 O4 P
• Molecular Weight: 202.147
• Hs Code.: 2919900090
• Mol file: 10113-28-7.mol

Synonyms:Dimethylphenyl phosphate; O,O-Dimethyl O-phenyl phosphate; Phenyl dimethyl phosphate;SV 5 oxon

Chemical Property of TRIS(PHENYL,METHYLPHENYL,ETHYLPHENYLANDNONYLPHENYL)PHOSPHATE

Chemical Property:

• Vapor Pressure: 0.121mmHg at 25°C
• Boiling Point: 226.7°Cat760mmHg
• Flash Point: 105.1°C
• PSA: 54.57000
• Density: 1.211g/cm³
• LogP: 2.46630

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIS(PHENYL,METHYLPHENYL,ETHYLPHENYLANDNONYLPHENYL)PHOSPHATE

There total 18 articles about TRIS(PHENYL,METHYLPHENYL,ETHYLPHENYLANDNONYLPHENYL)PHOSPHATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

Dimethyl phosphite (868-85-9) + phenol (108-95-2,27073-41-2) → dimethyl phenyl phosphate (10113-28-7)

Guidance literature:

With sodium iodide; In acetonitrile; at 20 ℃; for 2h; Electrochemical reaction; Green chemistry;

DOI:10.1039/d1ob00779c

Reference yield: 89.0%

methanol (67-56-1) + (1-phenyl)-N,N,N',N'-tetramethyldiamido phosphate (7393-13-7) → dimethyl phenyl phosphate (10113-28-7)

Guidance literature:

With boron trifluoride methanol complex; 1) 0 deg C, 1h, 2) RT, overnight;

DOI:10.1021/jo00016a042

Reference yield: 88.0%

Dimethyl chlorophosphate (813-77-4) + phenol (108-95-2,27073-41-2) → dimethyl phenyl phosphate (10113-28-7)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; In tetrahydrofuran; at 20 ℃; for 4h;

DOI:10.1055/s-0032-1317344 DOI:10.1055/s-0032-1317344

upstream raw materials:

O-phenyl phosphorodichloridate

phosphoric acid monophenyl ester

methyl 2,2,2-trichloroacetimidate

2,2-bis-methanesulfonyl-N-methyl-acetimidic acid methyl ester

Downstream raw materials:

Ammonium (3-hydroxypropyl), trimethyl hydroxide phenyl hydrogen phosphate, innersalt

trimethyl phosphite

phenol

O-methyl phenyl phosphonochloridothioate

Refernces

• 1、 Meyerson, Seymour,Harvan, Donald J.,Hass, J. Ronald,Ramirez, Fausto,Marecek, James F.. "The Monomeric Metaphosphate Anion in Negative-Ion Chemical-Ionization Mass Spectra of Phosphotriesters". . p. 6877 - 6883. Retrieved 1984.
• 2、 Yilmaz, Elvan,Bier, David,Guillory, Xavier,Briels, Jeroen,Ruiz-Blanco, Yasser B.,Sanchez-Garcia, Elsa,Ottmann, Christian,Kaiser, Markus. "Mono- and Bivalent 14-3-3 Inhibitors for Characterizing Supramolecular “Lysine Wrapping” of Oligoethylene Glycol (OEG) Moieties in Proteins". supporting information. p. 13807 - 13814. Retrieved 2018/09/14.
• 3、 Pisarek, Sabina,Bednarski, Hubert,Gryko, Dorota. "An efficient method for phosphorylation of alcohols: Preparation of porphyrin-derived phosphates". . p. 2667 - 2671,5. Retrieved 2012/12/12.