Lhcgbifhsccrrg-uhfffaoysa-

Base Information

• Chemical Name: Lhcgbifhsccrrg-uhfffaoysa-
• CAS No.: 10325-39-0
• Molecular Formula: BCl2 H
• Molecular Weight: 82.7249
• Nikkaji Number: J236.766A
• Mol file: 10325-39-0.mol

Synonyms:LHCGBIFHSCCRRG-UHFFFAOYSA-

Chemical Property of Lhcgbifhsccrrg-uhfffaoysa-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.99820
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 81.9548356
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(Cl)Cl

Technology Process of Lhcgbifhsccrrg-uhfffaoysa-

There total 53 articles about Lhcgbifhsccrrg-uhfffaoysa- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

monochlorodiborane (17927-57-0) + boron trichloride (10294-34-5) → dichloroborane (10325-39-0)

Guidance literature:

in presence of fluid BCl3; 100 % conversion at 20°C in 1 week; more than 60 % B2H5Cl reacts at 30°C in 4 h;

DOI:10.1021/ic50007a067

Reference yield: 86.4%

hydrogen (1333-74-0) + boron trichloride (10294-34-5) → dichloroborane (10325-39-0)

Guidance literature:

With magnesium; In gas; flowing H2/BCl3 gas mixt. over Mg heated to 440°C; molar ratio H2:BCl3 = 7.9:1;

Reference yield: 73.0%

pentaborane(9) + diboron tetrachloride (13701-67-2) → monochlorodiborane (17927-57-0) + 1-(dichloroboryl)pentaborane + dichloroborane (10325-39-0) + boron trichloride (10294-34-5) + diborane (19287-45-7)

Guidance literature:

In neat (no solvent); reaction carried out in Pyrex tubes to which Teflon valves had been sealed or in a N2-filled glovebox; reaction of B2Cl4 with excess B5H9 in a 1:3 mole ratio; vessel allowed to warm from -196 ° C to ambient temp., 20 min at ambient temp.,; fractionation, yield of 1-BCl2B5H8 based upon amt. of B2Cl4 employed: 73%, based upon amt. of B5H9 consumed: 95%; small amts. of B2H6, BCl2H, B2H5Cl, also material insufficiently volatileto move into vac. line formed;;

upstream raw materials:

boron trichloride

diborane

hydrogen

monochlorodiborane

Downstream raw materials:

2-dichloroboryl-2-methyl-2-(3-dichloroboryl-4-methylcyclohexyl)ethane

diphenyl sulfide

monochlorodiborane

diborane

Refernces

An efficient synthesis of N,N'-substituted symmetrical diamines

10.1080/00397919208019266

The study presents a novel and efficient method for synthesizing N,N'-substituted symmetrical diamines using diazidoalkanes and dichloroboranes. The researchers combined readily available starting materials, diazidoalkanes and dichloroboranes, in a one-pot procedure to produce the desired diamines in high yields. This method avoids the formation of polyalkylated by-products, which are commonly observed in reactions involving amines and alkyl halides. The synthesized diamines were characterized by 1H and 13C NMR spectroscopy, elemental analysis, and mass spectrometry. The study also extended this approach to the synthesis of thermine, a tetramine with biological significance, demonstrating the versatility and applicability of this synthetic route. The method offers distinct advantages over previous procedures, including the use of readily available starting materials, high yields, and simplified purification steps.