Formyl fluoride

Base Information

• Chemical Name: Formyl fluoride
• CAS No.: 1493-02-3
• Molecular Formula: CH F O
• Molecular Weight: 48.0167
• UNII: 0UY0U66165
• DSSTox Substance ID: DTXSID6073946
• Nikkaji Number: J404.105D
• Wikipedia: Formyl_fluoride
• Wikidata: Q3560492,Q82916773
• Mol file: 1493-02-3.mol

Synonyms:FORMYL FLUORIDE;1493-02-3;UNII-0UY0U66165;0UY0U66165;fluoroformaldehyde;Formic acid fluoride;CHFO;HFCO;C-H-F-O;FORMYL FLUORIDE [MI];DTXSID6073946;HYDROGEN CARBONYL FLUORIDE;Q3560492

Chemical Property of Formyl fluoride

Chemical Property:

• Vapor Pressure: 5180mmHg at 25°C
• Melting Point: -142°
• Boiling Point: bp760 -29°
• PSA: 17.07000
• Density: 1.004g/cm³
• LogP: 0.74820
• XLogP3: 0.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 48.001142813
• Heavy Atom Count: 3
• Complexity: 12.3

Purity/Quality:

99%, ^*data from raw suppliers

FORMYL FLUORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)F
• Uses: Acylating agent in organic synthesis.

Technology Process of Formyl fluoride

There total 14 articles about Formyl fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1,1,2-Trifluoroethan (430-66-0) → Carbonyl fluoride (353-50-4) + formyl fluoride (1493-02-3)

Guidance literature:

With air; chlorine; at 24.9 ℃; for 0.833333h; under 760 Torr; Product distribution; Mechanism; Irradiation;

DOI:10.1002/kin.550270105

Reference yield: 83.0%

4-Methyl-benzoic acid difluoromethyl ester (120608-85-7) → formyl fluoride (1493-02-3) + 4-methylbenzoyl fluoride (350-42-5)

Guidance literature:

With potassium fluoride; In 1,4-dioxane; at 110 ℃; for 10h;

DOI:10.1021/jo00274a012

Reference yield: 13.0%

1,1,2-trifluoroethylene (359-11-5) → trifluoroethylene oxide (2925-24-8) + Carbonyl fluoride (353-50-4) + formyl fluoride (1493-02-3) + trifluoroethylene ozonide (86013-87-8)

Guidance literature:

With ozone; In 1,1,2-Trichloro-1,2,2-trifluoroethane; at 0 ℃; Further byproducts given;

DOI:10.1021/ja00545a035

upstream raw materials:

formic acid

benzoyl fluoride

1-fluoroethylene

1,1,1,2-tetrafluoroethane

Downstream raw materials:

benzaldehyde

formic acid ethyl ester

N-formylethylamine

N-formyldiethylamine

Refernces

• 1、 M?gelberg, Trine E.,Sehested, Jens,Tyndall, Geoffrey S.,Orlando, John J.,Fracheboud, Jean-Marc,Wallington, Timothy J.. "Atmospheric chemistry of HFC-236cb: Fate of the alkoxy radical CF3CF2CFHO". . p. 2828 - 2832. Retrieved 1997.
• 2、 Rattigan, Oliver V.,Rowley, David M.,Wild, Oliver,Jones, Roderic L.,Cox, R. Anthony. "Mechanism of Atmospheric Oxidation of 1,1,1,2-Tetrafluoroethane (HFC 134a)". . p. 1819 - 1830. Retrieved 1994.
• 3、 Hasson,Moore,Smith. "Fluorine atom initiated oxidation of CF3CFH2 (HFC-134a) studied by FTIR spectroscopy". . p. 541 - 554. Retrieved 2007/10/03.