Decyl methyl sulfoxide

Base Information

• Chemical Name: Decyl methyl sulfoxide
• CAS No.: 3079-28-5
• Molecular Formula: C11H24OS
• Molecular Weight: 204.377
• Hs Code.: 2930909090
• European Community (EC) Number: 221-368-0
• UNII: GKV59F869B
• DSSTox Substance ID: DTXSID60863097
• Nikkaji Number: J101.634B
• Wikidata: Q27279150
• Mol file: 3079-28-5.mol

Synonyms:1-decyl methyl sulfoxide;N-decylmethyl sulfoxide;N-decylmethylsulfoxide

Chemical Property of Decyl methyl sulfoxide

Chemical Property:

• Vapor Pressure: 0.000438mmHg at 25°C
• Melting Point: 52-53 °C
• Refractive Index: 1.475
• Boiling Point: 325.4 °C at 760 mmHg
• Flash Point: 150.6 °C
• PSA: 36.28000
• Density: 0.93 g/cm³
• LogP: 4.37130
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 9
• Exact Mass: 204.15478656
• Heavy Atom Count: 13
• Complexity: 123

Purity/Quality:

98%Min ^*data from raw suppliers

DECYL METHYL SULFOXIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCS(=O)C

Technology Process of Decyl methyl sulfoxide

There total 9 articles about Decyl methyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-(methylthio)decane (22438-39-7) → decyl methyl sulfoxide (3079-28-5)

Guidance literature:

With sodium hypochlorite pentahydrate; In water; acetonitrile; at 20 ℃; for 0.15h; Green chemistry;

DOI:10.1055/s-0035-1560482

Reference yield: 88.0%

1-(methylthio)decane (22438-39-7) → decyl methyl sulfoxide (3079-28-5) + 1-(methylsulfonyl)decane (54863-62-6)

Guidance literature:

With oxygen; cis-{RuCl₂(Me₂SO)4}; In isopropyl alcohol; at 100 ℃; for 16h; under 5171.5 Torr; Kinetics; Thermodynamic data; Product distribution; E_a, ΔS⁺; further dihaloruthenium(II) complex catalysts; further sulfide substrates; further solvent; variation of temperature;

DOI:10.1021/ja00323a020

Reference yield: 82.0%

1-bromo-3-methanesulfinyl-benzene (29959-92-0) + n-decyl magnesium bromide (17049-50-2) → decyl methyl sulfoxide (3079-28-5)

Guidance literature:

In tetrahydrofuran; at 0 ℃; for 1.5h;

DOI:10.1021/jo991912q

upstream raw materials:

1-(methylthio)decane

1-bromo-4-(methylsulfinyl)benzene

n-decyl magnesium bromide

1-bromo-2-(methylsulfinyl)benzene